000849819 001__ 849819
000849819 005__ 20240711092247.0
000849819 0247_ $$2doi$$a10.1021/acs.energyfuels.8b00620
000849819 0247_ $$2ISSN$$a0887-0624
000849819 0247_ $$2ISSN$$a1520-5029
000849819 0247_ $$2WOS$$aWOS:000430783300142
000849819 037__ $$aFZJ-2018-03922
000849819 082__ $$a620
000849819 1001_ $$0P:(DE-HGF)0$$aJiao, Facun$$b0
000849819 245__ $$aSynergistic Mechanisms of CaCl 2 and CaO on the Vaporization of Cs from Cs-Doped Ash during Thermal Treatment
000849819 260__ $$aColumbus, Ohio$$bAmerican Chemical Society$$c2018
000849819 3367_ $$2DRIVER$$aarticle
000849819 3367_ $$2DataCite$$aOutput Types/Journal article
000849819 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1530856023_31468
000849819 3367_ $$2BibTeX$$aARTICLE
000849819 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000849819 3367_ $$00$$2EndNote$$aJournal Article
000849819 520__ $$aThis study aimed to clarify the roles of CaCl2, CaO, and their mixture in the vaporization of Cs from Cs-doped ash during thermal treatment. In particular, potential mechanisms of the synergistic effect of the addition of a mixture of CaCl2 and CaO on Cs vaporization were investigated. Vaporization experiments were carried out in a lab-scale horizontal furnace at 900, 1000, and 1100 °C. The results indicated that adding a mixture of CaCl2 and CaO produced a synergistic effect on Cs vaporization when the reaction temperature was above 1000 °C and the vaporization ratio was noticeably increased in comparison to that when adding CaCl2 or CaO alone. The formation of wadalite (Ca6Al5Si2O16Cl3) and/or igumnovite [Ca3Al2(SiO4)2Cl4], derived from chemical reactions among CaCl2, CaO, and aluminosilicates in the Cs-doped ash, delayed the release of Cl during thermal treatment, thus extending the contact time of Cs and gaseous Cl. Furthermore, CaO destabilized the aluminosilicate structure, resulting in a higher volatility and reactivity of Cs, and thus, a reaction readily occurred between activated Cs and gaseous Cl released from the decomposition of wadalite and/or igumnovite.
000849819 536__ $$0G:(DE-HGF)POF3-111$$a111 - Efficient and Flexible Power Plants (POF3-111)$$cPOF3-111$$fPOF III$$x0
000849819 588__ $$aDataset connected to CrossRef
000849819 7001_ $$0P:(DE-HGF)0$$aKinoshita, Norikazu$$b1
000849819 7001_ $$0P:(DE-HGF)0$$aKawaguchi, Masato$$b2
000849819 7001_ $$0P:(DE-HGF)0$$aAsada, Motoyuki$$b3
000849819 7001_ $$0P:(DE-HGF)0$$aHonda, Maki$$b4
000849819 7001_ $$0P:(DE-HGF)0$$aSueki, Keisuke$$b5
000849819 7001_ $$00000-0002-3523-9666$$aNinomiya, Yoshihiko$$b6$$eCorresponding author
000849819 7001_ $$0P:(DE-Juel1)159377$$aSergeev, Dmitry$$b7
000849819 7001_ $$00000-0002-6116-1604$$aBläsing, Marc$$b8
000849819 7001_ $$0P:(DE-Juel1)129765$$aMüller, Michael$$b9
000849819 773__ $$0PERI:(DE-600)1483539-3$$a10.1021/acs.energyfuels.8b00620$$gVol. 32, no. 4, p. 5433 - 5442$$n4$$p5433 - 5442$$tEnergy & fuels$$v32$$x1520-5029$$y2018
000849819 8564_ $$uhttps://juser.fz-juelich.de/record/849819/files/acs.energyfuels.8b00620.pdf$$yRestricted
000849819 8564_ $$uhttps://juser.fz-juelich.de/record/849819/files/acs.energyfuels.8b00620.gif?subformat=icon$$xicon$$yRestricted
000849819 8564_ $$uhttps://juser.fz-juelich.de/record/849819/files/acs.energyfuels.8b00620.jpg?subformat=icon-1440$$xicon-1440$$yRestricted
000849819 8564_ $$uhttps://juser.fz-juelich.de/record/849819/files/acs.energyfuels.8b00620.jpg?subformat=icon-180$$xicon-180$$yRestricted
000849819 8564_ $$uhttps://juser.fz-juelich.de/record/849819/files/acs.energyfuels.8b00620.jpg?subformat=icon-640$$xicon-640$$yRestricted
000849819 8564_ $$uhttps://juser.fz-juelich.de/record/849819/files/acs.energyfuels.8b00620.pdf?subformat=pdfa$$xpdfa$$yRestricted
000849819 909CO $$ooai:juser.fz-juelich.de:849819$$pVDB
000849819 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)159377$$aForschungszentrum Jülich$$b7$$kFZJ
000849819 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129765$$aForschungszentrum Jülich$$b9$$kFZJ
000849819 9131_ $$0G:(DE-HGF)POF3-111$$1G:(DE-HGF)POF3-110$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lEnergieeffizienz, Materialien und Ressourcen$$vEfficient and Flexible Power Plants$$x0
000849819 9141_ $$y2018
000849819 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000849819 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bENERG FUEL : 2015
000849819 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000849819 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000849819 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000849819 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000849819 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000849819 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000849819 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000849819 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology
000849819 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5
000849819 9201_ $$0I:(DE-Juel1)IEK-2-20101013$$kIEK-2$$lWerkstoffstruktur und -eigenschaften$$x0
000849819 980__ $$ajournal
000849819 980__ $$aVDB
000849819 980__ $$aI:(DE-Juel1)IEK-2-20101013
000849819 980__ $$aUNRESTRICTED
000849819 981__ $$aI:(DE-Juel1)IMD-1-20101013