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@ARTICLE{Jiao:849819,
      author       = {Jiao, Facun and Kinoshita, Norikazu and Kawaguchi, Masato
                      and Asada, Motoyuki and Honda, Maki and Sueki, Keisuke and
                      Ninomiya, Yoshihiko and Sergeev, Dmitry and Bläsing, Marc
                      and Müller, Michael},
      title        = {{S}ynergistic {M}echanisms of {C}a{C}l 2 and {C}a{O} on the
                      {V}aporization of {C}s from {C}s-{D}oped {A}sh during
                      {T}hermal {T}reatment},
      journal      = {Energy $\&$ fuels},
      volume       = {32},
      number       = {4},
      issn         = {1520-5029},
      address      = {Columbus, Ohio},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2018-03922},
      pages        = {5433 - 5442},
      year         = {2018},
      abstract     = {This study aimed to clarify the roles of CaCl2, CaO, and
                      their mixture in the vaporization of Cs from Cs-doped ash
                      during thermal treatment. In particular, potential
                      mechanisms of the synergistic effect of the addition of a
                      mixture of CaCl2 and CaO on Cs vaporization were
                      investigated. Vaporization experiments were carried out in a
                      lab-scale horizontal furnace at 900, 1000, and 1100 °C. The
                      results indicated that adding a mixture of CaCl2 and CaO
                      produced a synergistic effect on Cs vaporization when the
                      reaction temperature was above 1000 °C and the vaporization
                      ratio was noticeably increased in comparison to that when
                      adding CaCl2 or CaO alone. The formation of wadalite
                      (Ca6Al5Si2O16Cl3) and/or igumnovite [Ca3Al2(SiO4)2Cl4],
                      derived from chemical reactions among CaCl2, CaO, and
                      aluminosilicates in the Cs-doped ash, delayed the release of
                      Cl during thermal treatment, thus extending the contact time
                      of Cs and gaseous Cl. Furthermore, CaO destabilized the
                      aluminosilicate structure, resulting in a higher volatility
                      and reactivity of Cs, and thus, a reaction readily occurred
                      between activated Cs and gaseous Cl released from the
                      decomposition of wadalite and/or igumnovite.},
      cin          = {IEK-2},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {111 - Efficient and Flexible Power Plants (POF3-111)},
      pid          = {G:(DE-HGF)POF3-111},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000430783300142},
      doi          = {10.1021/acs.energyfuels.8b00620},
      url          = {https://juser.fz-juelich.de/record/849819},
}