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| 001 | 849819 | ||
| 005 | 20240711092247.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.energyfuels.8b00620 |2 doi |
| 024 | 7 | _ | |a 0887-0624 |2 ISSN |
| 024 | 7 | _ | |a 1520-5029 |2 ISSN |
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| 100 | 1 | _ | |a Jiao, Facun |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Synergistic Mechanisms of CaCl 2 and CaO on the Vaporization of Cs from Cs-Doped Ash during Thermal Treatment |
| 260 | _ | _ | |a Columbus, Ohio |c 2018 |b American Chemical Society |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a This study aimed to clarify the roles of CaCl2, CaO, and their mixture in the vaporization of Cs from Cs-doped ash during thermal treatment. In particular, potential mechanisms of the synergistic effect of the addition of a mixture of CaCl2 and CaO on Cs vaporization were investigated. Vaporization experiments were carried out in a lab-scale horizontal furnace at 900, 1000, and 1100 °C. The results indicated that adding a mixture of CaCl2 and CaO produced a synergistic effect on Cs vaporization when the reaction temperature was above 1000 °C and the vaporization ratio was noticeably increased in comparison to that when adding CaCl2 or CaO alone. The formation of wadalite (Ca6Al5Si2O16Cl3) and/or igumnovite [Ca3Al2(SiO4)2Cl4], derived from chemical reactions among CaCl2, CaO, and aluminosilicates in the Cs-doped ash, delayed the release of Cl during thermal treatment, thus extending the contact time of Cs and gaseous Cl. Furthermore, CaO destabilized the aluminosilicate structure, resulting in a higher volatility and reactivity of Cs, and thus, a reaction readily occurred between activated Cs and gaseous Cl released from the decomposition of wadalite and/or igumnovite. |
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| 700 | 1 | _ | |a Asada, Motoyuki |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Honda, Maki |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Sueki, Keisuke |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Ninomiya, Yoshihiko |0 0000-0002-3523-9666 |b 6 |e Corresponding author |
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| 700 | 1 | _ | |a Bläsing, Marc |0 0000-0002-6116-1604 |b 8 |
| 700 | 1 | _ | |a Müller, Michael |0 P:(DE-Juel1)129765 |b 9 |
| 773 | _ | _ | |a 10.1021/acs.energyfuels.8b00620 |g Vol. 32, no. 4, p. 5433 - 5442 |0 PERI:(DE-600)1483539-3 |n 4 |p 5433 - 5442 |t Energy & fuels |v 32 |y 2018 |x 1520-5029 |
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