TY  - JOUR
AU  - Kulikovsky, Andrei
TI  - Analytical low-current impedance of the cathode side of a PEM fuel cell
JO  - Journal of electroanalytical chemistry
VL  - 823
SN  - 1572-6657
CY  - New York, NY [u.a.]
PB  - Elsevier
M1  - FZJ-2018-04135
SP  - 335 - 341
PY  - 2018
AB  - We derive a simple compact expression for impedance of the cathode side of a PEM fuel cell working at a low current density. The solution includes the faradaic impedance, the impedances due to proton and oxygen transport in the cathode catalyst layer (CCL), and due to oxygen transport in the gas diffusion layer (GDL). The solution works if the cell current density is below 100 mA cm−2. Fitting the model impedance to the experimental spectrum gives the ORR Tafel slope, the double layer capacitance, and the transport parameters of the CCL and GDL.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000443664700041
DO  - DOI:10.1016/j.jelechem.2018.06.026
UR  - https://juser.fz-juelich.de/record/850053
ER  -