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100 1 _ |a Guhl, Conrad
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245 _ _ |a Interfaces in solid-state sodium-ion batteries: NaCoO$_2$ thin films on solid electrolyte substrates
260 _ _ |a New York, NY [u.a.]
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520 _ _ |a On the way to sodium-based all-solid-state batteries, interface analysis is a key issue. In this work, the interface between two typical solid sodium-ion conductors (Na-β″-Al2O3 and NASICON) and the layered oxide material NaCoO2 is investigated. The formation of the interface between the electrolyte material and the NaCoO2 coating is studied using an in-situ X-ray photoemission spectroscopy (XPS) surface science approach. Only a slight reduction of zirconium and scandium in NASICON was observed in proximity to the cathode side interface, while severe reactions, including the formation of a CaOAl2O3 mixed phase, were detected between Na-β″-Al2O3 and NaCoO2.
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700 1 _ |a Kehne, Philipp
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700 1 _ |a Ma, Qianli
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700 1 _ |a Tietz, Frank
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700 1 _ |a Komissinskiy, Philipp
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700 1 _ |a Jaegermann, Wolfram
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700 1 _ |a Hausbrand, René
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773 _ _ |a 10.1016/j.electacta.2018.02.109
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