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@ARTICLE{Chandrasekaran:851014,
author = {Chandrasekaran, Anand and Wei, Xian-Kui and Feigl, Ludwig
and Damjanovic, Dragan and Setter, Nava and Marzari, Nicola},
title = {{A}symmetric structure of 90 ∘ domain walls and
interactions with defects in {P}b{T}i{O} 3},
journal = {Physical review / B},
volume = {93},
number = {14},
issn = {2469-9950},
address = {Woodbury, NY},
publisher = {Inst.},
reportid = {FZJ-2018-04728},
pages = {144102},
year = {2016},
abstract = {We investigate the atomistic structure of
ferroelastic-ferroelectric 90∘ domain walls in PbTiO3 with
first-principles calculations and high-resolution scanning
transmission electron microscopy. We find sharp
discontinuities in the variation of lattice parameters
across the domain walls. Unexpectedly, the two neighboring
domains become asymmetric across the boundary, giving rise
to primitive unit cells with large tetragonality ratios
(c/a) of the order of 1.11 close to the boundary. The
variation of the domain wall structure with respect to
strain is demonstrated. We show that oxygen vacancies are
attracted to the plane adjacent to the 90∘ domain wall.
The mechanisms of domain wall pinning by oxygen vacancies is
explained based on the energy landscape of the vacancies in
the presence of the domain interface.},
cin = {PGI-5},
ddc = {530},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000373311500003},
doi = {10.1103/PhysRevB.93.144102},
url = {https://juser.fz-juelich.de/record/851014},
}