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000851106 1001_ $$0P:(DE-HGF)0$$aDagger, Tim$$b0
000851106 245__ $$aInvestigating the lithium ion battery electrolyte additive tris (2,2,2-trifluoroethyl) phosphite by gas chromatography with a flame ionization detector (GC-FID)
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000851106 520__ $$aThe quantification of lithium ion battery electrolyte additives provides challenges in terms of methods and instrumentation. In this work, the detectability of the flame retardant additive tris(2,2,2-trifluoroethyl) phosphite (TTFPi) differs unusually when added to a standard electrolyte (1 M LiPF6 in ethylene carbonate (EC)[thin space (1/6-em)]:[thin space (1/6-em)]dimethyl carbonate (DMC) 1[thin space (1/6-em)]:[thin space (1/6-em)]1 wt%) using gas chromatography with a flame ionization detector (GC-FID). In this work, nuclear magnetic resonance (NMR), ion trap time of flight mass spectrometry (IT-TOF™ MS) and gas chromatography-mass spectrometry (GC-MS) are used to investigate a pure TTFPi solution and a standard battery electrolyte with TTFPi as an additive with regard to parasitic TTFPi consuming reactions and different TTFPi concentrations, respectively. NMR and IT-TOF™ MS measurements confirm the chemical stability of the TTFPi/standard electrolyte mixture and concentration dependent GC-MS and GC-FID experiments indicate a premature FID saturation limit for TTFPi in presence of standard electrolyte. The findings explain the counterintuitive absence of TTFPi for higher concentrations and provide important information for future sample preparation.
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000851106 7001_ $$0P:(DE-HGF)0$$aHenschel, Jonas$$b1
000851106 7001_ $$0P:(DE-Juel1)167131$$aRezaei Rad, Babak$$b2$$ufzj
000851106 7001_ $$0P:(DE-HGF)0$$aLürenbaum, Constantin$$b3
000851106 7001_ $$0P:(DE-HGF)0$$aSchappacher, Falko M.$$b4
000851106 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b5$$ufzj
000851106 7001_ $$00000-0003-1508-6073$$aNowak, Sascha$$b6$$eCorresponding author
000851106 773__ $$0PERI:(DE-600)2623224-8$$a10.1039/C7RA09476K$$gVol. 7, no. 84, p. 53048 - 53055$$n84$$p53048 - 53055$$tRSC Advances$$v7$$x2046-2069$$y2017
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