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| 100 | 1 | _ | |a Dagger, Tim |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Investigating the lithium ion battery electrolyte additive tris (2,2,2-trifluoroethyl) phosphite by gas chromatography with a flame ionization detector (GC-FID) |
| 260 | _ | _ | |a London |c 2017 |b RSC Publishing |
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| 520 | _ | _ | |a The quantification of lithium ion battery electrolyte additives provides challenges in terms of methods and instrumentation. In this work, the detectability of the flame retardant additive tris(2,2,2-trifluoroethyl) phosphite (TTFPi) differs unusually when added to a standard electrolyte (1 M LiPF6 in ethylene carbonate (EC)[thin space (1/6-em)]:[thin space (1/6-em)]dimethyl carbonate (DMC) 1[thin space (1/6-em)]:[thin space (1/6-em)]1 wt%) using gas chromatography with a flame ionization detector (GC-FID). In this work, nuclear magnetic resonance (NMR), ion trap time of flight mass spectrometry (IT-TOF™ MS) and gas chromatography-mass spectrometry (GC-MS) are used to investigate a pure TTFPi solution and a standard battery electrolyte with TTFPi as an additive with regard to parasitic TTFPi consuming reactions and different TTFPi concentrations, respectively. NMR and IT-TOF™ MS measurements confirm the chemical stability of the TTFPi/standard electrolyte mixture and concentration dependent GC-MS and GC-FID experiments indicate a premature FID saturation limit for TTFPi in presence of standard electrolyte. The findings explain the counterintuitive absence of TTFPi for higher concentrations and provide important information for future sample preparation. |
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| 700 | 1 | _ | |a Nowak, Sascha |0 0000-0003-1508-6073 |b 6 |e Corresponding author |
| 773 | _ | _ | |a 10.1039/C7RA09476K |g Vol. 7, no. 84, p. 53048 - 53055 |0 PERI:(DE-600)2623224-8 |n 84 |p 53048 - 53055 |t RSC Advances |v 7 |y 2017 |x 2046-2069 |
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