% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Kasnatscheew:851122,
author = {Kasnatscheew, Johannes and Börner, Markus and Streipert,
Benjamin and Meister, Paul and Wagner, Ralf and Cekic
Laskovic, Isidora and Winter, Martin},
title = {{L}ithium ion battery cells under abusive discharge
conditions: {E}lectrode potential development and
interactions between positive and negative electrode},
journal = {Journal of power sources},
volume = {362},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2018-04824},
pages = {278 - 282},
year = {2017},
abstract = {Increasing specific energy of lithium ion battery cells
(LIBs) and their cycle life requires deeper understanding of
complex processes taking place during the cell operation.
This work focuses on the electrode potential development and
the interactions between negative and positive electrode in
a quasi LIB full cell by applying over-discharge conditions.
By analysis of the potential profiles, a characteristic
potential plateau at ≈ 3.56 V vs. Li/Li+ was detected at
the graphite negative electrode, which can be assigned to
the Cu oxidation process of the negative electrode current
collector. Also at the positive electrode, a time shifted
potential plateau was observed, which could be attributed to
a competitive reaction between conventional discharge
(lithiation) and parasitic Cu reduction (plating) on the
positive electrode surface. The proposed mechanism involving
the presence of elemental Cu on the positive electrode
surface was confirmed by SEM-EDX mapping experiments. The
relevance of Cu dissolution and deposition as well as
possible solution approaches are discussed.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000408288600032},
doi = {10.1016/j.jpowsour.2017.07.044},
url = {https://juser.fz-juelich.de/record/851122},
}