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@ARTICLE{Rser:851131,
      author       = {Röser, Stephan and Lerchen, Andreas and Ibing, Lukas and
                      Cao, Xia and Kasnatscheew, Johannes and Glorius, Frank and
                      Winter, Martin and Wagner, Ralf},
      title        = {{H}ighly {E}ffective {S}olid {E}lectrolyte
                      {I}nterphase-{F}orming {E}lectrolyte {A}dditive {E}nabling
                      {H}igh {V}oltage {L}ithium-{I}on {B}atteries},
      journal      = {Chemistry of materials},
      volume       = {29},
      number       = {18},
      issn         = {1520-5002},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2018-04833},
      pages        = {7733 - 7739},
      year         = {2017},
      abstract     = {The electrochemical and thermal stabilities of commonly
                      used LiPF6/organic carbonate-based electrolytes are still a
                      bottleneck for the development of high energy density
                      lithium-ion batteries (LIBs) operating at elevated cell
                      voltage and elevated temperature. The use of intrinsic
                      electrochemically stable electrolyte solvents, e.g. sulfones
                      or dinitriles, has been reported as one approach to enable
                      high voltage LIBs. However, the major challenge of these
                      solvents is related to their poor reductive stability and
                      lack of solid electrolyte interphase (SEI)-forming ability
                      on the graphite electrode. Here,
                      3-methyl-1,4,2-dioxazol-5-one (MDO) is synthesized and
                      investigated as new highly effective SEI-forming electrolyte
                      additive which can sufficiently suppress electrolyte
                      reduction and graphite exfoliation in propylene carbonate
                      (PC)-based electrolytes. With the addition of only 2 wt $\%$
                      MDO, LiNi0.5Mn0.3Co0.2O2 (NMC532)/graphite full cells
                      containing a 1 M LiPF6 in PC electrolyte reach a cycle life
                      of more than 450 cycles while still having a capacity
                      retention of $80\%.$ In addition, MDO has proven to be
                      oxidatively stable until potentials as high as 5.3 V vs
                      Li/Li+. Further development of MDO and its derivatives as
                      electrolyte additives is a step forward to high voltage
                      stable electrolyte formulations based on alternative
                      electrolyte solvents and high energy density LIBs.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000411918900014},
      doi          = {10.1021/acs.chemmater.7b01977},
      url          = {https://juser.fz-juelich.de/record/851131},
}