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@ARTICLE{Pyschik:851132,
      author       = {Pyschik, Marcelina and Winter, Martin and Nowak, Sascha},
      title        = {{R}eactions of the {A}dditive 1,3–{P}ropane {S}ultone
                      with {E}lectrolyte {C}ompounds {I}nvestigated by {C}apillary
                      {E}lectrophoresis and {H}igh-{R}esolution {M}ass
                      {S}pectrometry},
      journal      = {Electrochimica acta},
      volume       = {251},
      issn         = {0013-4686},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2018-04834},
      pages        = {573 - 580},
      year         = {2017},
      abstract     = {In this study, the lithium ion battery (LIB) additive
                      1,3-propane sultone (PS) was investigated using capillary
                      electrophoresis (CE) connected to a quadrupole
                      time-of-flight mass spectrometer (Q-TOF MS). In the first
                      part, PS was thermally aged with the organophosphates
                      dimethyl phosphate (DMP), diethyl phosphate (DEP) or
                      triethyl phosphate (TEP) at 60 °C for one month. It was
                      observed that PS reacted with traces of water, with
                      organophosphates, with decomposition products of the
                      organophosphates and polymerized to long-chain decomposition
                      products. Due to the large number of in part similar
                      decomposition products, it was not possible to baseline
                      separate them from each other. The structures of the
                      decomposition products were identified and the deviations of
                      the detected m/z-ratios of the decomposition products to the
                      calculated m/z-ratios were lower than 3.0 ppm. Moreover, one
                      of the most interesting aspects was the formation of DEP in
                      the aged samples of TEP and PS. In the second part, PS was
                      mixed with DMP, DEP or TEP in the LIB electrolyte and aged
                      at 60 °C for one month. In these samples, decomposition
                      products were determined, formed by reaction of PS with
                      carbonates, organophosphates and DMP, DEP or TEP. In these
                      electropherograms, the decomposition products were baseline
                      separated.In this study, the high reactivity of PS with
                      different electrolyte compounds from the electrolyte was
                      shown in battery research for the first time.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000413004200061},
      doi          = {10.1016/j.electacta.2017.08.092},
      url          = {https://juser.fz-juelich.de/record/851132},
}