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@ARTICLE{Bieker:851133,
      author       = {Bieker, Georg and Wellmann, Julia and Kolek, Martin and
                      Jalkanen, Kirsi and Winter, Martin and Bieker, Peter},
      title        = {{I}nfluence of cations in lithium and magnesium
                      polysulphide solutions: dependence of the solvent chemistry},
      journal      = {Physical chemistry, chemical physics},
      volume       = {19},
      number       = {18},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {FZJ-2018-04835},
      pages        = {11152 - 11162},
      year         = {2017},
      abstract     = {In order to gain a deeper understanding of Li and Mg
                      polysulphides in Li/S and Mg/S batteries, respectively, this
                      work investigates the impact of the two different cations as
                      well as the influence of the electrolyte solvents' relative
                      dielectric permittivity and Gutmann's donor number on the
                      solubility and relative stability of different Li and Mg
                      polysulphide species. Therefore, the disproportionation and
                      dissociation equilibria of chemically prepared “Li2S8”
                      and “MgS8” solutions in DMSO, DMF, ACN, THF, DME,
                      TEGDME, and Pyr14TFSI are characterized by UV/Vis
                      spectroscopy. Varying the cation and the solvent reveals
                      their mutual interplay in stabilizing different polysulphide
                      species. To our knowledge, this is the first time that
                      chemically synthesized Mg polysulphides in solutions are
                      studied. The results of this work provide essential
                      knowledge for further development of the economically,
                      ecologically, and also in terms of energy density and
                      safety, attractive Mg/S batteries.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:28425529},
      UT           = {WOS:000401022300019},
      doi          = {10.1039/C7CP01238A},
      url          = {https://juser.fz-juelich.de/record/851133},
}