% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Stenzel:851213,
      author       = {Stenzel, Yannick Philipp and Winter, Martin and Nowak,
                      Sascha},
      title        = {{E}valuation of different plasma conditions and resolutions
                      for understanding elemental organophosphorus analysis via
                      {GC}-{ICP}-{SF}-{MS}},
      journal      = {Journal of analytical atomic spectrometry},
      volume       = {33},
      number       = {6},
      issn         = {1364-5544},
      address      = {Cambridge},
      publisher    = {ChemSoc},
      reportid     = {FZJ-2018-04913},
      pages        = {1041 - 1048},
      year         = {2018},
      abstract     = {The state-of-the-art electrolyte in lithium ion battery
                      application is composed of a solvent mixture of organic
                      carbonates and lithium hexafluorophosphate (LiPF6) as the
                      conducting salt. Decomposition reactions of the
                      hexafluorophosphate anion with the organic carbonates and
                      trace amounts of water in the system result in a large
                      variety of organofluorophosphates. The toxicity of
                      organofluorophosphates has been known for some time and is
                      now drawing interest in the battery research context.
                      Molecular standards are not available as these compounds are
                      supposedly highly toxic, generally unknown or just recently
                      described. Therefore, in this study, the organophosphates
                      formed were investigated with gas chromatography-inductively
                      coupled plasma-sector field-mass spectrometry
                      (GC-ICP-SF-MS). With this setup, it was possible to overcome
                      the need for molecular standards and to perform
                      quantification after separation of species using only one
                      external standard. Comprehensive data of the phosphorus
                      signals were evaluated in different resolution modes (R >
                      300 and R > 4000) and under different plasma conditions (wet
                      and dry). Thereby, possible interferences originating from
                      aerosol entry, GC solvents, sample matrix or decomposition
                      products could be detected and evaluated. The developed
                      phosphorus speciation procedures and tuning techniques were
                      interrelated. Detection and quantification limits were
                      determined for all setups and additionally, preliminary
                      qualitative and quantitative investigations of different
                      commercially available electrolytes after thermal treatment
                      are presented.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000434680700012},
      doi          = {10.1039/C8JA00092A},
      url          = {https://juser.fz-juelich.de/record/851213},
}