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@ARTICLE{Zhang:851229,
author = {Zhang, Yi-Xin and Ma, Zheng and Ge, Zhen-Hua and Qin, Peng
and Zheng, Fengshan and Feng, Jing},
title = {{H}ighly enhanced thermoelectric properties of {C}u 1.8 {S}
by introducing {P}b{S}},
journal = {Journal of alloys and compounds},
volume = {764},
issn = {0925-8388},
address = {Lausanne},
publisher = {Elsevier},
reportid = {FZJ-2018-04929},
pages = {738 - 744},
year = {2018},
abstract = {Digenite (Cu1.8S) has attracted extensive attention as
candidate for use in thermoelectric applications due to its
low-cost, low-toxicity characteristics, but the
thermoelectric (TE) property is still not good. In this
work, PbS was used for improving TE properties of
polycrystalline Cu1.8S bulk. Cu1.8S+ x $wt\%$ PbS
(x = 0, 0.5, 1, 2, 3) bulk samples were fabricated via
mechanical alloying (MA) and spark plasma sintering (SPS)
techniques. The effects of adding PbS on the TE performance
of Cu1.8S were investigated in detail at the temperature
between 323 K and 773 K. According to the results,
introducing PbS is an efficient approach for optimizing the
TE properties of Cu1.8S, which is mainly due to the
maintained electrical transport properties by the regulated
hole carrier concentration and the modified band structure,
as well as the reduced the thermal conductivity by the
generated point defect and additional interfaces. An optimum
thermoelectric figure of merit (ZT) value of 1.1 was
obtained at 773 K for the Cu1.8S sample with $2 wt\%$
PbS, which is 2.2 times higher than that of the pristine
Cu1.8S (0.49 at 773 K).},
cin = {PGI-5},
ddc = {670},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000444058300089},
doi = {10.1016/j.jallcom.2018.06.116},
url = {https://juser.fz-juelich.de/record/851229},
}