Home > Publications database > Monolithic All-Phosphate Solid-State Lithium-Ion Battery with Improved Interfacial Compatibility > print

001     851351
005     20240712112832.0
024 7 _ |a 10.1021/acsami.8b05902
|2 doi
024 7 _ |a 1944-8244
|2 ISSN
024 7 _ |a 1944-8252
|2 ISSN
024 7 _ |a pmid:29894641
|2 pmid
024 7 _ |a WOS:000438179000055
|2 WOS
024 7 _ |a altmetric:46727802
|2 altmetric
037 _ _ |a FZJ-2018-05036
082 _ _ |a 540
100 1 _ |0 P:(DE-Juel1)161141
|a Yu, Shicheng
|b 0
|e Corresponding author
245 _ _ |a Monolithic All-Phosphate Solid-State Lithium-Ion Battery with Improved Interfacial Compatibility
260 _ _ |a Washington, DC
|b Soc.
|c 2018
336 7 _ |2 DRIVER
|a article
336 7 _ |2 DataCite
|a Output Types/Journal article
336 7 _ |0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
|a Journal Article
|b journal
|m journal
|s 1536153462_464
336 7 _ |2 BibTeX
|a ARTICLE
336 7 _ |2 ORCID
|a JOURNAL_ARTICLE
336 7 _ |0 0
|2 EndNote
|a Journal Article
520 _ _ |a High interfacial resistance between solid electrolyte and electrode of ceramic all-solid-state batteries is a major reason for the reduced performance of these batteries. A solid-state battery using a monolithic all-phosphate concept based on screen printed thick LiTi2(PO4)3 anode and Li3V2(PO4)3 cathode composite layers on a densely sintered Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte has been realized with competitive cycling performance. The choice of materials was primarily based on the (electro-)chemical and mechanical matching of the components instead of solely focusing on high-performance of individual components. Thus, the battery utilized a phosphate backbone in combination with tailored morphology of the electrode materials to ensure good interfacial matching for a durable mechanical stability. Moreover, the operating voltage range of the active materials matches with the intrinsic electrochemical window of the electrolyte which resulted in high electrochemical stability. A highly competitive discharge capacity of 63.5 mAh g–1 at 0.39 C after 500 cycles, corresponding to 84% of the initial discharge capacity, was achieved. The analysis of interfacial charge transfer kinetics confirmed the structural and electrical properties of the electrodes and their interfaces with the electrolyte, as evidenced by the excellent cycling performance of the all-phosphate solid-state battery. These interfaces have been studied via impedance analysis with subsequent distribution of relaxation times analysis. Moreover, the prepared solid-state battery could be processed and operated in air atmosphere owing to the low oxygen sensitivity of the phosphate materials. The analysis of electrolyte/electrode interfaces after cycling demonstrates that the interfaces remained stable during cycling.
536 _ _ |0 G:(DE-HGF)POF3-131
|a 131 - Electrochemical Storage (POF3-131)
|c POF3-131
|f POF III
|x 0
588 _ _ |a Dataset connected to CrossRef
700 1 _ |0 P:(DE-Juel1)166415
|a Mertens, Andreas
|b 1
|u fzj
700 1 _ |0 P:(DE-Juel1)161208
|a Tempel, Hermann
|b 2
|u fzj
700 1 _ |0 P:(DE-Juel1)161348
|a Schierholz, Roland
|b 3
|u fzj
700 1 _ |0 P:(DE-Juel1)157700
|a Kungl, Hans
|b 4
|u fzj
700 1 _ |0 P:(DE-Juel1)156123
|a Eichel, Rüdiger-A.
|b 5
|u fzj
773 _ _ |0 PERI:(DE-600)2467494-1
|a 10.1021/acsami.8b05902
|g Vol. 10, no. 26, p. 22264 - 22277
|n 26
|p 22264 - 22277
|t ACS applied materials & interfaces
|v 10
|x 1944-8252
|y 2018
856 4 _ |u https://juser.fz-juelich.de/record/851351/files/acsami.8b05902.pdf
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/851351/files/acsami.8b05902.pdf?subformat=pdfa
|x pdfa
|y Restricted
909 C O |o oai:juser.fz-juelich.de:851351
|p VDB
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)161141
|a Forschungszentrum Jülich
|b 0
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)161208
|a Forschungszentrum Jülich
|b 2
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)161348
|a Forschungszentrum Jülich
|b 3
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)157700
|a Forschungszentrum Jülich
|b 4
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)156123
|a Forschungszentrum Jülich
|b 5
|k FZJ
910 1 _ |0 I:(DE-588b)36225-6
|6 P:(DE-Juel1)156123
|a RWTH Aachen
|b 5
|k RWTH
913 1 _ |0 G:(DE-HGF)POF3-131
|1 G:(DE-HGF)POF3-130
|2 G:(DE-HGF)POF3-100
|a DE-HGF
|l Speicher und vernetzte Infrastrukturen
|v Electrochemical Storage
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
|b Energie
914 1 _ |y 2018
915 _ _ |0 StatID:(DE-HGF)0200
|2 StatID
|a DBCoverage
|b SCOPUS
915 _ _ |0 StatID:(DE-HGF)0300
|2 StatID
|a DBCoverage
|b Medline
915 _ _ |0 StatID:(DE-HGF)0310
|2 StatID
|a DBCoverage
|b NCBI Molecular Biology Database
915 _ _ |0 StatID:(DE-HGF)0100
|2 StatID
|a JCR
|b ACS APPL MATER INTER : 2015
915 _ _ |0 StatID:(DE-HGF)0199
|2 StatID
|a DBCoverage
|b Thomson Reuters Master Journal List
915 _ _ |0 StatID:(DE-HGF)0110
|2 StatID
|a WoS
|b Science Citation Index
915 _ _ |0 StatID:(DE-HGF)0150
|2 StatID
|a DBCoverage
|b Web of Science Core Collection
915 _ _ |0 StatID:(DE-HGF)0111
|2 StatID
|a WoS
|b Science Citation Index Expanded
915 _ _ |0 StatID:(DE-HGF)1150
|2 StatID
|a DBCoverage
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |0 StatID:(DE-HGF)1160
|2 StatID
|a DBCoverage
|b Current Contents - Engineering, Computing and Technology
915 _ _ |0 StatID:(DE-HGF)9905
|2 StatID
|a IF >= 5
|b ACS APPL MATER INTER : 2015
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)IEK-9-20110218
|k IEK-9
|l Grundlagen der Elektrochemie
|x 0
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)IEK-9-20110218
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IET-1-20110218

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21