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000851478 1001_ $$00000-0002-6183-1129$$aNapso, Sofia$$b0$$eCorresponding author
000851478 245__ $$aStructural Analysis of Cellulose-Coated Oil-in-Water Emulsions Fabricated from Molecular Solution
000851478 260__ $$aWashington, DC$$bACS Publ.$$c2018
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000851478 520__ $$aNatural cellulose has been used as a coating to stabilize oil-in-water (o/w) emulsions by exploiting the amphiphilic character of the cellulose chains molecularly dissolved in the ionic liquid 1-ethyl-3-methylimidazolium acetate. Its cellulose coating exhibits a continuous amorphous structure which differs significantly from the cellulose particle stabilization used in Pickering emulsions. The structure of these cellulose-coated o/w emulsion particles, in particular the cellulose coating shell characteristics (thickness, porosity, and composition), is studied by using a combination of direct imaging methods such as cryogenic electron microscopy and fluorescence microscopy with small-angle neutron scattering measurements. This work suggests a unique multicompartment structure of the emulsion particles: an oil core, surrounded by an inner shell composed of a porous cellulose gel, encapsulated by a dense outer cellulose shell, a few nanometers in thickness. The thickness of the inner cellulose shell varies significantly. The nanoscale emulsion droplets exhibit a thickness of 10 ± 3 nm, whereas the larger micron-sized droplets exhibit a thicker inner cellulose shell of 500–750 nm. It is also inferred that the cellulose shells contain water rather than oil.
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000851478 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x0
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000851478 7001_ $$0P:(DE-HGF)0$$aRein, Dmitry M.$$b1
000851478 7001_ $$0P:(DE-Juel1)130647$$aFu, Zhendong$$b2
000851478 7001_ $$0P:(DE-Juel1)130905$$aRadulescu, Aurel$$b3
000851478 7001_ $$0P:(DE-HGF)0$$aCohen, Yachin$$b4
000851478 773__ $$0PERI:(DE-600)2005937-1$$a10.1021/acs.langmuir.8b01325$$gVol. 34, no. 30, p. 8857 - 8865$$n30$$p8857 - 8865$$tLangmuir$$v34$$x1520-5827$$y2018
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