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@PHDTHESIS{Maurer:851752,
author = {Maurer, Claudia},
title = {{L}aser {T}reatment of {S}ilicon {T}hin-{F}ilms for
{P}hotovoltaic {A}pplications},
volume = {432},
school = {RWTH Aachen},
type = {Dissertation},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2018-05277},
isbn = {978-3-95806-347-1},
series = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {vii, 165 S.},
year = {2018},
note = {RWTH Aachen, Diss., 2018},
abstract = {Thin-film silicon is an important material in the fields of
photovoltaics. As well as microcrystalline (μc-Si:H),
amorphous (a-Si:H) silicon has been used for a long as an
absorber in thin-film solar cells. Moreover, the surface
passivation of c-Si wafers for heterojunction solar cells is
achieved with a-Si:H. In addition, a-Si:H is used as
precursor for tunnel oxide passivated contacts. Here, a
post-deposition thermal treatment of the a-Si:Hlayer is
mandatory. In doing so, the amorphoussilicon develops
crystalline phases. This annealing step is conducted at high
temperatures, risking damage to the tunnel oxide. As a
consequence, there is the idea of replacing amorphous
silicon with microcrystalline silicon. In this work, the
influence of a laser treatment on the structural, electrical
and optical properties of a-Si:H and μc-Si:H was
investigated. The diffusion of hydrogen for a-Si:H on glass
substrates is thus of special interest. Firstly, the
eligibility of Raman spectroscopy to evaluate the influence
of a laser treatmenton the hydrogen concentration and the
microstructure was studied. Therefore,a-Si:H was deposited
on infrared transparent substrates. After deposition, the
samples were annealed at different temperatures in a
furnace. These samples were also analyzed with Fourier
Transform Infrared Spectroscopy, a well-established method,
in addition to Raman spectroscopy. The comparison of both
analysis methods proved that Raman spectroscopy can be used
to determine the relative change of the hydrogen
concentration of amorphous silicon. In addition, the
qualitative evolution of the microstructure parameter is
competitive. As a result, Raman spectroscopy can be used to
evaluate the influence of a Laser treatmenton the hydrogen
concentration and the microstructure parameter of amorphous
silicon. [...]},
cin = {IEK-5},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
urn = {urn:nbn:de:0001-2018091928},
url = {https://juser.fz-juelich.de/record/851752},
}