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@ARTICLE{Yalcinkaya:856730,
      author       = {Yalcinkaya, Hacer and Feoktystov, Artem and Gradzielski,
                      Michael},
      title        = {{F}ormation of {W}ell-{D}efined {V}esicles by {S}tyrene
                      {A}ddition to a {N}onionic {S}urfactant and {T}heir
                      {P}olymerization {L}eading to {V}iscous {H}ybrid {S}ystems},
      journal      = {Langmuir},
      volume       = {34},
      number       = {31},
      issn         = {1520-5827},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {FZJ-2018-06081},
      pages        = {9184 - 9194},
      year         = {2018},
      abstract     = {Self-assembled structures in aqueous solutions can be fixed
                      by polymerization after adding hydrophobic monomers and can
                      thereby be used as templates which allows to substantially
                      alter the properties of these systems. In this work, we
                      started from a self-assembled micellar system consisting of
                      the nonionic surfactants tetradecyldimethylamine oxid
                      (TDMAO) and Pluronic L35 to which styrene was added as a
                      polymerizable monomer. Interestingly, it was observed that
                      styrene induces a transition from micelles to well-defined
                      vesicles in a similar manner as a typical cosurfactant. The
                      structural transition of the aggregates upon styrene
                      addition as well as the structures formed after initiating a
                      polymerization reaction were investigated by means of
                      turbidity, dynamic and static light scattering, (DLS, SLS),
                      small angle neutron scattering (SANS), and rheology
                      measurements. Especially the scattering results confirmed
                      the interesting effect of styrene on the mesoscopic
                      structure and showed a structural evolution from rod-like
                      micelles for low styrene concentrations to vesicles at
                      intermediate styrene amounts, and then finally the formation
                      of microemulsion droplets for high styrene content. Their
                      polymerization of the vesicles again leads to a shape change
                      to wormlike, polymerized aggregates, whose presence then
                      results in rather viscous systems. In contrast, the
                      microemulsions with higher styrene content then are
                      templated and retain their size after polymerization,
                      thereby leading to nanolatices.},
      cin          = {JCNS-FRM-II / JCNS-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-2-20110106},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6G15 - FRM II / MLZ (POF3-6G15)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:30010346},
      UT           = {WOS:000441477300009},
      doi          = {10.1021/acs.langmuir.8b01377},
      url          = {https://juser.fz-juelich.de/record/856730},
}