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@ARTICLE{Schleicher:856757,
author = {Schleicher, Sebastian and Borca, Bogdana and Rawson,
Jeffrey and Matthes, Frank and Bürgler, Daniel E. and
Kögerler, Paul and Schneider, Claus M.},
title = {{U}ltra-{H}igh {V}acuum {D}eposition of {P}yrene
{M}olecules on {M}etal {S}urfaces},
journal = {Physica status solidi / B},
volume = {255},
number = {10},
issn = {0370-1972},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2018-06101},
pages = {1800235},
year = {2018},
abstract = {Interfacial properties of organic adsorbates featuring
aromatic π‐orbitals on metal surfaces play an important
role for organic electronics and spintronics. Pyrene is a
flat aromatic molecule with a size between ultimately small
benzene and extended graphene segments. The deposition of
pyrene molecules onto clean and reactive surfaces with a
sub‐monolayer coverage under ultra‐high vacuum (UHV)
conditions is challenging, since pyrene is a solid with a
high vapor pressure. Here, a sublimation procedure under UHV
and image pyrene adlayers on in situ prepared Au(111) and
Fe/W(110) substrates by means of low‐temperature scanning
tunneling microscopy is presented. For Au(111), the
molecule–surface interaction is weak as indicated by the
specific herringbone reconstruction of the Au(111) surface
that is visible through the self‐assembled pyrene adlayer.
Pyrene desorption due to weak intermolecular interaction
self‐limits the growth to one monolayer (ML). On the more
reactive 2–4 ML thick Fe films on W(110), the molecular
order of the pyrene adlayer sensitively depends on the Fe
thickness‐dependent dislocation pattern at the substrate
surface. Irregular arrangements occur for 1 ML Fe and near
substrate dislocations for 2–4 ML Fe. Self‐assembled
ordered arrays form predominantly for 2 ML Fe, where the
dislocation pattern leaves sufficiently large unperturbed
areas between the dislocation lines.},
cin = {PGI-6 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)PGI-6-20110106 / $I:(DE-82)080009_20140620$},
pnm = {522 - Controlling Spin-Based Phenomena (POF3-522)},
pid = {G:(DE-HGF)POF3-522},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000447304700016},
doi = {10.1002/pssb.201800235},
url = {https://juser.fz-juelich.de/record/856757},
}