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000857257 1001_ $$0P:(DE-HGF)0$$aAssaf, Emmanuel$$b0$$eCorresponding author
000857257 245__ $$aExperimental and theoretical investigation of the reaction of RO 2 radicals with OH radicals: Dependence of the HO 2 yield on the size of the alkyl group
000857257 260__ $$aNew York, NY$$bWiley$$c2018
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000857257 520__ $$aThe HO2 yield in the reaction of peroxy radicals with OH radicals has been determined experimentally at 50 Torr helium by measuring simultaneously OH and HO2 concentration time profiles, following the photolysis of XeF2 in the presence of different hydrocarbons and O2. The following yields have been obtained: urn:x-wiley:05388066:media:kin21191:kin21191-math-0001 = (0.90 ± 0.1), urn:x-wiley:05388066:media:kin21191:kin21191-math-0002 = (0.75 ± 0.15), urn:x-wiley:05388066:media:kin21191:kin21191-math-0003 = (0.41 ± 0.08), and urn:x-wiley:05388066:media:kin21191:kin21191-math-0004 = (0.15 ± 0.03). The clear decrease in HO2 yield with increasing size of the alkyl moiety can be explained by an increased stabilization of the trioxide adduct, ROOOH. This has been confirmed by ab initio and Rice–Ramsperger–Kassel–Marcus master equation calculations. Extrapolation of the experimental results to atmospheric conditions shows that the stabilized adduct, ROOOH, is the nearly exclusive product of the reaction between OH radicals and peroxy radicals containing more than three C‐atoms. The fate and possible impact of these species is completely unexplored so far.
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000857257 7001_ $$0P:(DE-HGF)0$$aSchoemaecker, Coralie$$b1
000857257 7001_ $$0P:(DE-Juel1)167140$$aVereecken, Luc$$b2
000857257 7001_ $$00000-0003-0932-432X$$aFittschen, Christa$$b3
000857257 773__ $$0PERI:(DE-600)1480875-4$$a10.1002/kin.21191$$gVol. 50, no. 9, p. 670 - 680$$n9$$p670 - 680$$tInternational journal of chemical kinetics$$v50$$x0538-8066$$y2018
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