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@ARTICLE{Assaf:857257,
      author       = {Assaf, Emmanuel and Schoemaecker, Coralie and Vereecken,
                      Luc and Fittschen, Christa},
      title        = {{E}xperimental and theoretical investigation of the
                      reaction of {RO} 2 radicals with {OH} radicals: {D}ependence
                      of the {HO} 2 yield on the size of the alkyl group},
      journal      = {International journal of chemical kinetics},
      volume       = {50},
      number       = {9},
      issn         = {0538-8066},
      address      = {New York, NY},
      publisher    = {Wiley},
      reportid     = {FZJ-2018-06486},
      pages        = {670 - 680},
      year         = {2018},
      abstract     = {The HO2 yield in the reaction of peroxy radicals with OH
                      radicals has been determined experimentally at 50 Torr
                      helium by measuring simultaneously OH and HO2 concentration
                      time profiles, following the photolysis of XeF2 in the
                      presence of different hydrocarbons and O2. The following
                      yields have been obtained:
                      urn:x-wiley:05388066:media:kin21191:kin21191-math-0001 =
                      (0.90 ± 0.1),
                      urn:x-wiley:05388066:media:kin21191:kin21191-math-0002 =
                      (0.75 ± 0.15),
                      urn:x-wiley:05388066:media:kin21191:kin21191-math-0003 =
                      (0.41 ± 0.08), and
                      urn:x-wiley:05388066:media:kin21191:kin21191-math-0004 =
                      (0.15 ± 0.03). The clear decrease in HO2 yield with
                      increasing size of the alkyl moiety can be explained by an
                      increased stabilization of the trioxide adduct, ROOOH. This
                      has been confirmed by ab initio and
                      Rice–Ramsperger–Kassel–Marcus master equation
                      calculations. Extrapolation of the experimental results to
                      atmospheric conditions shows that the stabilized adduct,
                      ROOOH, is the nearly exclusive product of the reaction
                      between OH radicals and peroxy radicals containing more than
                      three C‐atoms. The fate and possible impact of these
                      species is completely unexplored so far.},
      cin          = {IEK-8},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {243 - Tropospheric trace substances and their
                      transformation processes (POF3-243)},
      pid          = {G:(DE-HGF)POF3-243},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000439930100005},
      doi          = {10.1002/kin.21191},
      url          = {https://juser.fz-juelich.de/record/857257},
}