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@ARTICLE{Bunkan:857259,
      author       = {Bunkan, A. J. C. and Srinivasulu, G. and Amedro, D. and
                      Vereecken, L. and Wallington, T. J. and Crowley, J. N.},
      title        = {{P}roducts and mechanism of the {OH}-initiated
                      photo-oxidation of perfluoro ethyl vinyl ether, {C} 2 {F} 5
                      {OCF}={CF} 2},
      journal      = {Physical chemistry, chemical physics},
      volume       = {20},
      number       = {16},
      issn         = {1463-9084},
      address      = {Cambridge},
      publisher    = {RSC Publ.66479},
      reportid     = {FZJ-2018-06488},
      pages        = {11306 - 11316},
      year         = {2018},
      abstract     = {The OH-initiated photo-oxidation of perfluoro ethyl vinyl
                      ether (C2F5OCF[double bond, length as m-dash]CF2, PEVE) in
                      air (298 K, 50 and 750 Torr total pressure) was studied in a
                      photochemical reactor using in situ detection of PEVE and
                      its products by Fourier transform IR absorption
                      spectroscopy. The relative rate technique was used to derive
                      the rate coefficient, k1, for the reaction of PEVE with OH
                      as k1 = (2.8 ± 0.3) × 10−12 cm3 molecule−1 s−1. The
                      photo-oxidation of PEVE in the presence of NOx at 1 bar
                      results in formation of C2F5OCFO, FC(O)C(O)F and CF2O in
                      molar yields of 0.50 ± 0.07, 0.46 ± 0.07 and 1.50 ± 0.22,
                      respectively. FC(O)C(O)F and CF2O are formed partially in
                      secondary, most likely heterogeneous processes. At a reduced
                      pressure of 50 Torr, the product distribution is shifted
                      towards formation of FC(O)C(O)F, indicating the important
                      role of collisional quenching of initially formed
                      association complexes, and enabling details of the reaction
                      mechanism to be elucidated. An atmospheric photo-oxidation
                      mechanism for PEVE is presented and the environmental
                      implications of PEVE release and degradation are discussed.},
      cin          = {IEK-8},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {243 - Tropospheric trace substances and their
                      transformation processes (POF3-243)},
      pid          = {G:(DE-HGF)POF3-243},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29637965},
      UT           = {WOS:000431821800068},
      doi          = {10.1039/C8CP01392F},
      url          = {https://juser.fz-juelich.de/record/857259},
}