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@ARTICLE{Assaf:857260,
      author       = {Assaf, Emmanuel and Schoemaecker, Coralie and Vereecken,
                      Luc and Fittschen, Christa},
      title        = {{T}he reaction of fluorine atoms with methanol: yield of
                      {CH} 3 {O}/{CH} 2 {OH} and rate constant of the reactions
                      {CH} 3 {O} + {CH} 3 {O} and {CH} 3 {O} + {HO} 2},
      journal      = {Physical chemistry, chemical physics},
      volume       = {20},
      number       = {16},
      issn         = {1463-9084},
      address      = {Cambridge},
      publisher    = {RSC Publ.66479},
      reportid     = {FZJ-2018-06489},
      pages        = {10660 - 10670},
      year         = {2018},
      abstract     = {Xenondifluoride, XeF2, has been photolysed in the presence
                      of methanol, CH3OH. Two reaction pathways are possible: F +
                      CH3OH → CH2OH + HF and F + CH3OH → CH3O + HF. Both
                      products, CH2OH and CH3O, will be converted to HO2 in the
                      presence of O2. The rate constants for the reaction of both
                      radicals with O2 differ by more than 3 orders of magnitude,
                      which allows an unequivocal distinction between the two
                      reactions when measuring HO2 concentrations in the presence
                      of different O2 concentrations. The following yields have
                      then been determined from time-resolved HO2 profiles:
                      ϕCH2OH = (0.497 ± 0.013) and ϕCH3O = (0.503 ± 0.013).
                      Experiments under low O2 concentrations lead to reaction
                      mixtures containing nearly equal amounts of HO2 (converted
                      from the first reaction) and CH3O (from the second
                      reaction). The subsequent HO2 decays are very sensitive to
                      the rate constants of the reaction between these two
                      radicals and the following rate constants have been
                      obtained: k(CH3O + CH3O) = (7.0 ± 1.4) × 10−11 cm3 s−1
                      and k(CH3O + HO2) = (1.1 ± 0.2) × 10−10 cm3 s−1. The
                      latter reaction has also been theoretically investigated on
                      the CCSD(T)//M06-2X/aug-cc-pVTZ level of theory and CH3OH +
                      O2 have been identified as the main products. Using μVTST,
                      a virtually pressure independent rate constant of k(CH3O +
                      HO2) = 4.7 × 10−11 cm3 s−1 has been obtained, in good
                      agreement with the experiment.},
      cin          = {IEK-8},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {243 - Tropospheric trace substances and their
                      transformation processes (POF3-243)},
      pid          = {G:(DE-HGF)POF3-243},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29139501},
      UT           = {WOS:000431821800008},
      doi          = {10.1039/C7CP05770A},
      url          = {https://juser.fz-juelich.de/record/857260},
}