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@ARTICLE{Dagger:857790,
      author       = {Dagger, Tim and Meier, Vladislav and Hildebrand, Stephan
                      and Brüggemann, Daniel and Winter, Martin and Schappacher,
                      Falko M.},
      title        = {{S}afety {P}erformance of 5 {A}h {L}ithium {I}on
                      {B}attery {C}ells {C}ontaining the {F}lame {R}etardant
                      {E}lectrolyte {A}dditive ({P}henoxy)
                      {P}entafluorocyclotriphosphazene},
      journal      = {Journal of applied pharmacy},
      volume       = {6},
      number       = {10},
      issn         = {2194-4288},
      address      = {[S.l.]},
      reportid     = {FZJ-2018-06757},
      pages        = {2001 - 2010},
      year         = {2018},
      abstract     = {Investigations on the effect of flame retardant additives
                      (FRs) on the abuse tolerance of large scale lithium ion
                      battery (LIB) cells (5 Ah) are of high relevance in
                      battery science and industry but rarely performed as they
                      are cost and time consuming. In addition, even though FRs
                      are frequently investigated, their positive effect on the
                      safety properties of larger full LIB cells under abusive
                      condition has not been proven yet. The promising FR
                      (phenoxy) pentafluorocyclotriphosphazene (FPPN) is known to
                      exhibit excellent flame retardant‐ and electrochemical
                      properties at the same time. Therefore, FPPN is investigated
                      towards abuse tolerance in 5 Ah LIB cells in this study.
                      Calorimetric investigations show that a mass percentage of
                      $5 wt \%$ FPPN mixed to a standard electrolyte,
                      significantly reduces the self‐heating rate of 5 Ah
                      cells in the temperature range from 80 °C to 110 °C.
                      While nail penetration and external short circuit
                      experiments provide no significant difference between
                      standard and FPPN‐containing cells, an increased
                      overcharge tolerance and a favorable thermal stability at
                      ≈120 °C in overcharge and oven experiments could be
                      shown.},
      cin          = {IEK-12},
      ddc          = {610},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000449676400019},
      doi          = {10.1002/ente.201800131},
      url          = {https://juser.fz-juelich.de/record/857790},
}