Gast ::
| Hauptseite > Publikationsdatenbank > Development of new pyrazole-based lithium salts for battery applications – Do established basic design concepts really work? > print |
| Hauptseite > Publikationsdatenbank > Development of new pyrazole-based lithium salts for battery applications – Do established basic design concepts really work? > print |
| 001 | 857797 | ||
| 005 | 20240712113049.0 | ||
| 024 | 7 | _ | |a 10.1016/j.electacta.2018.08.055 |2 doi |
| 024 | 7 | _ | |a 0013-4686 |2 ISSN |
| 024 | 7 | _ | |a 1873-3859 |2 ISSN |
| 024 | 7 | _ | |a WOS:000445133700036 |2 WOS |
| 037 | _ | _ | |a FZJ-2018-06764 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Grünebaum, Mariano |0 P:(DE-Juel1)166392 |b 0 |e Corresponding author |u fzj |
| 245 | _ | _ | |a Development of new pyrazole-based lithium salts for battery applications – Do established basic design concepts really work? |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2018 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1575010278_25885 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a This work is focused on applying structural concepts and basic chemical principles to model two N-heterocyclic lithium salts, based on trifluoromethyl substituted pyrazolide anions. An easily upscalable preparation method without difficult purification steps was also developed. In a comparative study, the physicochemical properties of the two new lithium salts were investigated, particularly the effect of an additional BF3-group at the nitrogen atom. In comparison to non-substituted lithium pyrazolide, the BF3-addition led to a strong improvement of thermal and electrochemical stability, ionic conductivity, as well as better C-rate and cycling performance. Furthermore, the anodic stability of Al current collectors was investigated and compared to commercial lithium salts, namely LiPF6 and lithium bis((trifluoromethyl)sulfonyl)imide (LiTFSI). Possible mechanisms that lead to the presented improvements are discussed. |
| 536 | _ | _ | |a 131 - Electrochemical Storage (POF3-131) |0 G:(DE-HGF)POF3-131 |c POF3-131 |f POF III |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 700 | 1 | _ | |a Buchheit, Annika |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Krause, Daniel |0 P:(DE-Juel1)173840 |b 2 |u fzj |
| 700 | 1 | _ | |a Hiller, Martin Manuel |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Schmidt, Christina |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 5 |u fzj |
| 700 | 1 | _ | |a Wiemhöfer, Hans-Dieter |0 P:(DE-Juel1)176785 |b 6 |u fzj |
| 773 | _ | _ | |a 10.1016/j.electacta.2018.08.055 |g Vol. 286, p. 313 - 323 |0 PERI:(DE-600)1483548-4 |p 313 - 323 |t Electrochimica acta |v 286 |y 2018 |x 0013-4686 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/857797/files/1-s2.0-S0013468618318425-main.pdf |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/857797/files/1-s2.0-S0013468618318425-main.pdf?subformat=pdfa |x pdfa |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:857797 |p VDB |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)166392 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)173840 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)166130 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 6 |6 P:(DE-Juel1)176785 |
| 913 | 1 | _ | |a DE-HGF |l Speicher und vernetzte Infrastrukturen |1 G:(DE-HGF)POF3-130 |0 G:(DE-HGF)POF3-131 |2 G:(DE-HGF)POF3-100 |v Electrochemical Storage |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |b Energie |
| 914 | 1 | _ | |y 2019 |
| 915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b ELECTROCHIM ACTA : 2017 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0310 |2 StatID |b NCBI Molecular Biology Database |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a IF >= 5 |0 StatID:(DE-HGF)9905 |2 StatID |b ELECTROCHIM ACTA : 2017 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|