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@ARTICLE{Otteny:857831,
      author       = {Otteny, Fabian and Kolek, Martin and Becking, Jens and
                      Winter, Martin and Bieker, Peter and Esser, Birgit},
      title        = {{U}nlocking {F}ull {D}ischarge {C}apacities of
                      {P}oly(vinylphenothiazine) as {B}attery {C}athode {M}aterial
                      by {D}ecreasing {P}olymer {M}obility {T}hrough
                      {C}ross-{L}inking},
      journal      = {Advanced energy materials},
      volume       = {8},
      number       = {33},
      issn         = {1614-6832},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2018-06798},
      pages        = {1802151 -},
      year         = {2018},
      abstract     = {Organic cathode materials are a sustainable alternative to
                      transition metal oxide‐based compounds in high voltage
                      rechargeable batteries due to their low toxicity and
                      availability from less‐limited resources. Important
                      criteria in their design are a high specific capacity,
                      cycling stability, and rate capability. Furthermore, the
                      cathode should contain a high mass loading of active
                      material and be compatible with different anode materials,
                      allowing for its use in a variety of cell designs. Here,
                      cross‐linked poly(3‐vinyl‐N‐methylphenothiazine) as
                      cathode‐active material is presented, which shows a
                      remarkable rate capability (up to 10C) and cycling stability
                      at a high and stable potential of 3.55 V versus Li/Li+ and a
                      specific capacity of 112 mAh g−1. Its use in full cells
                      with a high mass loading of 70 $wt\%$ is demonstrated
                      against lithium titanate as intercalation material as well
                      as lithium metal, which both show excellent performance.
                      Through comparison with
                      poly(3‐vinyl‐N‐methylphenothiazine) the study shows
                      that changing the structure of the redox‐active polymer
                      through cross‐linking can lead to a change in
                      charge/discharge mechanism and cycling behavior of the
                      composite electrode.
                      Poly(3‐vinyl‐N‐methylphenothiazine) in its cross‐
                      and non‐cross‐linked form both show excellent results as
                      cathode‐active materials with variable specifications
                      regarding specific capacity, cycling stability, and rate
                      capability.},
      cin          = {IEK-12},
      ddc          = {050},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000451181900002},
      doi          = {10.1002/aenm.201802151},
      url          = {https://juser.fz-juelich.de/record/857831},
}