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@ARTICLE{Modisha:858310,
      author       = {Modisha, Phillimon M. and Jordaan, Johan H. L. and
                      Bösmann, Andreas and Wasserscheid, Peter and Bessarabov,
                      Dmitri},
      title        = {{A}nalysis of reaction mixtures of perhydro-dibenzyltoluene
                      using two-dimensional gas chromatography and single
                      quadrupole gas chromatography},
      journal      = {International journal of hydrogen energy},
      volume       = {43},
      number       = {11},
      issn         = {0360-3199},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2018-07198},
      pages        = {5620 - 5636},
      year         = {2018},
      abstract     = {Energy storage via liquid organic hydrogen carrier (LOHC)
                      systems has gained significant attention in recent times. A
                      dibenzyltoluene (DBT) based LOHC offers excellent properties
                      which largely solve today's hydrogen storage challenges.
                      Understanding the course of the dehydrogenation reaction is
                      important for catalyst and process optimization. Therefore,
                      reliable and exact methods to determine the degree of
                      hydrogenation (doh) are important. We here present other
                      possible techniques, namely: comprehensive two-dimensional
                      gas chromatography coupled with time of flight mass
                      spectrometry (2D-GC-TOF-MS) and single quadrupole-mass
                      spectrometry gas chromatogram system (GC-SQ-MS). The
                      2D-GC-TOF-MS results indicate that isomer fractions lose
                      three molecules of hydrogen, as follows: H18-DBT, H12-DBT,
                      H6-DBT and H0-DBT, and the doh decreases with an increase in
                      dehydrogenation temperature. 1H NMR and GC-SQ-MS were
                      employed as additional analytical techniques. The GC-SQ-MS
                      was also used to analyse decomposition products that result
                      from thermal cracking of reaction mixture molecules.},
      cin          = {IEK-11},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-11-20140314},
      pnm          = {134 - Electrolysis and Hydrogen (POF3-134)},
      pid          = {G:(DE-HGF)POF3-134},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000429399500017},
      doi          = {10.1016/j.ijhydene.2018.02.005},
      url          = {https://juser.fz-juelich.de/record/858310},
}