Hauptseite > Workflowsammlungen > Publikationsgebühren > Impact of Trifluoromethylation of Adiponitrile on Aluminum Dissolution Behavior in Dinitrile-Based Electrolytes > print

001     858317
005     20240712113049.0
024 7 _ |a 10.1149/2.0461816jes
|2 doi
024 7 _ |a 0013-4651
|2 ISSN
024 7 _ |a 0096-4743
|2 ISSN
024 7 _ |a 0096-4786
|2 ISSN
024 7 _ |a 1945-6859
|2 ISSN
024 7 _ |a 1945-7111
|2 ISSN
024 7 _ |a 2002-2015
|2 ISSN
024 7 _ |a 2156-7395
|2 ISSN
024 7 _ |a 2128/24267
|2 Handle
024 7 _ |a WOS:000452659900002
|2 WOS
037 _ _ |a FZJ-2018-07205
082 _ _ |a 660
100 1 _ |a Oldiges, Kristina
|0 P:(DE-Juel1)168152
|b 0
245 _ _ |a Impact of Trifluoromethylation of Adiponitrile on Aluminum Dissolution Behavior in Dinitrile-Based Electrolytes
260 _ _ |a Pennington, NJ
|c 2018
|b Electrochemical Soc.
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1580979822_16208
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a Aluminum dissolution behavior of adiponitrile (ADN) and its trifluoromethylated derivative 3-(trifluoromethyl)adiponitrile (ADN-CF3) as single or co-solvent with propylene carbonate (PC) was determined in electrolytes with lithium bis(trifluoromethylsulfonyl) imide (LiTFSI) as conducting salt via selected electrochemical, spectroscopic and physicochemical methods. ADN-CF3 is introduced as a promising electrolyte solvent affording reduced aluminum dissolution in the presence of imide salts. In cases where neither electrolyte components nor decomposition products thereof enable the formation of protective surface layers on aluminum current collectors, both the viscosity and relative permittivity of the solvents could be identified as key parameters for reducing aluminum dissolution. High viscosities reduce the mobility of involved species yielding increased complex formation of Li+ and TFSI− ions or solvent molecules, hindering a reaction of TFSI− anions with the passivating aluminum oxide surface to Al(TFSI)x. Low relative permittivity yields lesser ionic dissociation of the lithium salt and lower solubility of Al(TFSI)x species in viscous electrolytes. Hence, reduced aluminum dissolution was observed by substituting electrolyte solvents from PC to ADN to ADN-CF3. The obtained results significantly contribute to better understanding of anodic aluminum dissolution behavior, while encouraging future design of advanced electrolytes with high viscosities and low-permittivity solvents that possess high oxidative stabilities.
536 _ _ |a 131 - Electrochemical Storage (POF3-131)
|0 G:(DE-HGF)POF3-131
|c POF3-131
|f POF III
|x 0
588 _ _ |a Dataset connected to CrossRef
700 1 _ |a von Aspern, Natascha
|0 P:(DE-Juel1)168328
|b 1
700 1 _ |a Cekic-Laskovic, Isidora
|0 P:(DE-Juel1)171204
|b 2
700 1 _ |a Winter, Martin
|0 P:(DE-Juel1)166130
|b 3
700 1 _ |a Brunklaus, Gunther
|0 P:(DE-Juel1)172047
|b 4
|e Corresponding author
773 _ _ |a 10.1149/2.0461816jes
|g Vol. 165, no. 16, p. A3773 - A3781
|0 PERI:(DE-600)2002179-3
|n 16
|p A3773 - A3781
|t Journal of the Electrochemical Society
|v 165
|y 2018
|x 0013-4651
856 4 _ |u https://juser.fz-juelich.de/record/858317/files/Invoice%282%29.pdf
856 4 _ |x pdfa
|u https://juser.fz-juelich.de/record/858317/files/Invoice%282%29.pdf?subformat=pdfa
856 4 _ |y OpenAccess
|u https://juser.fz-juelich.de/record/858317/files/J.%20Electrochem.%20Soc.-2018-Oldiges-A3773-81.pdf
856 4 _ |y OpenAccess
|x pdfa
|u https://juser.fz-juelich.de/record/858317/files/J.%20Electrochem.%20Soc.-2018-Oldiges-A3773-81.pdf?subformat=pdfa
909 C O |o oai:juser.fz-juelich.de:858317
|p openaire
|p open_access
|p OpenAPC
|p driver
|p VDB
|p openCost
|p dnbdelivery
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 0
|6 P:(DE-Juel1)168152
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 1
|6 P:(DE-Juel1)168328
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 2
|6 P:(DE-Juel1)171204
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 3
|6 P:(DE-Juel1)166130
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 4
|6 P:(DE-Juel1)172047
913 1 _ |a DE-HGF
|l Speicher und vernetzte Infrastrukturen
|1 G:(DE-HGF)POF3-130
|0 G:(DE-HGF)POF3-131
|2 G:(DE-HGF)POF3-100
|v Electrochemical Storage
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
|b Energie
914 1 _ |y 2019
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1160
|2 StatID
|b Current Contents - Engineering, Computing and Technology
915 _ _ |a Creative Commons Attribution CC BY 4.0
|0 LIC:(DE-HGF)CCBY4
|2 HGFVOC
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b J ELECTROCHEM SOC : 2017
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
915 _ _ |a WoS
|0 StatID:(DE-HGF)0110
|2 StatID
|b Science Citation Index
915 _ _ |a WoS
|0 StatID:(DE-HGF)0111
|2 StatID
|b Science Citation Index Expanded
915 _ _ |a IF < 5
|0 StatID:(DE-HGF)9900
|2 StatID
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
920 1 _ |0 I:(DE-Juel1)IEK-12-20141217
|k IEK-12
|l Helmholtz-Institut Münster Ionenleiter für Energiespeicher
|x 0
980 1 _ |a APC
980 1 _ |a FullTexts
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a I:(DE-Juel1)IEK-12-20141217
980 _ _ |a APC
981 _ _ |a I:(DE-Juel1)IMD-4-20141217

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21