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000858369 1001_ $$00000-0002-4355-3030$$aChyrkin, A.$$b0$$eCorresponding author
000858369 245__ $$aStability of External α-Al2O3 Scales on Alloy 602 CA at 1100–1200 °C
000858369 260__ $$aDordrecht [u.a.]$$bSpringer Science + Business Media B.V$$c2018
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000858369 520__ $$aAn external ultrathin α-Al2O3 scale grown on the Ni-base alloy 602 CA during air oxidation at 800 °C was characterized by means of high-resolution TEM/EDX and electron diffraction. Alloy samples pre-oxidized at 800 °C were subsequently exposed at 1100, 1150 and 1200 °C for up to 100 h. Whereas the external alumina remained stable at 1100 °C, with the increasing exposure temperature, the pre-grown alumina scale tended to break down resulting in an external chromia scale accompanied by internal alumina precipitation. The transition from external to internal Al oxidation was investigated using SEM/EDX/EBSD. The critical Al depletion at the scale-alloy interface during the post-exposure at 1100–1200 °C was modeled using the CALPHAD-based thermodynamic-kinetic approach.
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000858369 7001_ $$0P:(DE-Juel1)162507$$aGaliullin, T.$$b3
000858369 7001_ $$0P:(DE-Juel1)129810$$aWessel, E.$$b4
000858369 7001_ $$0P:(DE-Juel1)145209$$aGrüner, D.$$b5
000858369 7001_ $$0P:(DE-Juel1)129782$$aQuadakkers, W. J.$$b6
000858369 773__ $$0PERI:(DE-600)2018581-9$$a10.1007/s11085-017-9827-0$$gVol. 90, no. 1-2, p. 119 - 133$$n1-2$$p119 - 133$$tOxidation of metals$$v90$$x1573-4889$$y2018
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