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000858485 1001_ $$0P:(DE-Juel1)168104$$aLiu, Yang$$b0$$ufzj
000858485 245__ $$aA novel 10-membered macrocyclic lactone from the mangrove-derived endophytic fungus Annulohypoxylon sp.
000858485 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2018
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000858485 520__ $$aA novel 10-membered macrolactone, hypoxylide (1), was isolated from the endophytic fungus Annulohypoxylon sp. that was obtained from the Mangrove plant Rhizophora racemosa. The structure and absolute configuration of 1 were unambiguously elucidated by comprehensive 1D and 2D NMR, as well as by HRESIMS and ECD spectroscopic analyses. Hypoxylide (1) features an unprecedented polyketide skeleton comprised of a trihydroxynaphthalene-dione moiety fused to a decalactone ring. A plausible biosynthetic pathway of this novel metabolite is proposed.
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000858485 7001_ $$0P:(DE-HGF)0$$aKurtán, Tibor$$b1
000858485 7001_ $$0P:(DE-HGF)0$$aMándi, Attila$$b2
000858485 7001_ $$0P:(DE-HGF)0$$aWeber, Horst$$b3
000858485 7001_ $$0P:(DE-HGF)0$$aWang, Changyun$$b4
000858485 7001_ $$0P:(DE-Juel1)132001$$aHartmann, Rudolf$$b5$$ufzj
000858485 7001_ $$0P:(DE-HGF)0$$aLin, Wenhan$$b6
000858485 7001_ $$00000-0002-1636-6424$$aDaletos, Georgios$$b7
000858485 7001_ $$0P:(DE-HGF)0$$aProksch, Peter$$b8$$eCorresponding author
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