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000858487 1001_ $$00000-0002-2440-4427$$aAncheeva, Elena$$b0
000858487 245__ $$aChaetolines A and B, Pyrano[3,2- f ]isoquinoline Alkaloids from Cultivation of Chaetomium sp. in the Presence of Autoclaved Pseudomonas aeruginosa
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000858487 520__ $$aThe first members of a new alkaloid class, chaetolines A (1) and B (2), which feature a pyrano[3,2-f]isoquinoline core structure, were obtained from a crude extract of the fungal endophyte Chaetomium sp. after cultivation in the presence of autoclaved Pseudomonas aeruginosa. The structures of the new compounds, including the absolute configuration of the major stereoisomer, were determined through detailed analysis of HRESIMS, 1D/2D NMR, and calculation of ECD data. The possible biosynthetic origin of the unprecedented scaffold of 1 and 2 is proposed. The current study provides further evidence for mixed fermentation as a powerful tool to induce the accumulation of cryptic fungal natural products even in the absence of viable bacterial cells.
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000858487 7001_ $$00000-0002-7867-7084$$aMándi, Attila$$b1
000858487 7001_ $$0P:(DE-HGF)0$$aKirály, Sándor B.$$b2
000858487 7001_ $$0P:(DE-HGF)0$$aKurtán, Tibor$$b3
000858487 7001_ $$0P:(DE-Juel1)132001$$aHartmann, Rudolf$$b4$$ufzj
000858487 7001_ $$0P:(DE-HGF)0$$aAkone, Sergi H.$$b5
000858487 7001_ $$0P:(DE-HGF)0$$aWeber, Horst$$b6
000858487 7001_ $$00000-0002-1636-6424$$aDaletos, Georgios$$b7
000858487 7001_ $$0P:(DE-HGF)0$$aProksch, Peter$$b8$$eCorresponding author
000858487 773__ $$0PERI:(DE-600)1491522-4$$a10.1021/acs.jnatprod.8b00373$$gVol. 81, no. 11, p. 2392 - 2398$$n11$$p2392 - 2398$$tJournal of natural products$$v81$$x1520-6025$$y2018
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