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@ARTICLE{Stuckart:858629,
      author       = {Stuckart, Maria and Izarova, Natalya V. and vanLeusen, Jan
                      and Smekhova, Alevtina and Schmitz-Antoniak, Carolin and
                      Bamberger, Heiko and vanSlageren, Joris and
                      Santiago-Schübel, Beatrix and Kögerler, Paul},
      title        = {{H}ost-{G}uest-{I}nduced {E}nvironment {T}uning of 3d
                      {I}ons in a {P}olyoxopalladate {M}atrix},
      journal      = {Chemistry - a European journal},
      volume       = {24},
      number       = {67},
      issn         = {0947-6539},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2018-07489},
      pages        = {17767 - 17778},
      year         = {2018},
      abstract     = {A series of unprecedented supramolecular associates of
                      phenylarsonate‐capped {MIIPdII12O8}‐type (M=Co, Ni and
                      Zn) polyoxopalladates with α‐cyclodextrins (α‐CD) was
                      obtained and characterized in the solid state
                      (single‐crystal X‐ray diffraction (XRD), FT‐IR
                      spectroscopy, elemental and thermogravimetric (TGA)
                      analyses), in aqueous solution (1H and 13C NMR) and in the
                      gas phase (ESI‐MS). The non‐covalent host–guest
                      interactions between the organopolyoxoanions and α‐CD
                      rings alter the O8 coordination environment of a 3d
                      transition metal ion (MII) situated at the center of a
                      cuboid polyoxododecapalladate shell. This synthetically
                      controlled “chemical pressure” effectively induces axial
                      distortion of the otherwise cubic polyoxopalladate
                      environment between two trans‐positioned α‐CD moieties.
                      Its effect on the magnetic properties and the electronic
                      structure of the CoII derivative was assessed in a combined
                      SQUID magnetometry, EPR, X‐ray magnetic circular/linear
                      dichroism (XMCD/XMLD), and X‐ray absorption near‐edge
                      structure (XANES) spectroscopy study.},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {522 - Controlling Spin-Based Phenomena (POF3-522)},
      pid          = {G:(DE-HGF)POF3-522},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:30261127},
      UT           = {WOS:000451888300021},
      doi          = {10.1002/chem.201803531},
      url          = {https://juser.fz-juelich.de/record/858629},
}