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@ARTICLE{Schmitz:858631,
      author       = {Schmitz, Sebastian and Kovalchuk, Andrew and
                      Martín-Rodríguez, Alejandro and van Leusen, Jan and
                      Izarova, Natalya V. and Bourone, Svenja D. M. and Ai, Yong
                      and Ruiz, Eliseo and Chiechi, Ryan C. and Kögerler, Paul
                      and Monakhov, Kirill},
      title        = {{E}lement-{S}elective {M}olecular {C}harge {T}ransport
                      {C}haracteristics of {B}inuclear
                      {C}opper({II})-{L}anthanide({III}) {C}omplexes},
      journal      = {Inorganic chemistry},
      volume       = {57},
      number       = {15},
      issn         = {1520-510X},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2018-07491},
      pages        = {9274 - 9285},
      year         = {2018},
      abstract     = {A series of isostructural dinuclear 3d-4f complexes,
                      isolated as [CuLn(L·SMe)2(OOCMe)2(NO3)]·xMeOH (Ln = Gd 1,
                      Tb 2, Dy 3, and Y 4; x = 0.75–1) and comprising one
                      acetate and two thioether-Schiff base (L·SMe–) bridging
                      ligands based on 4-(methylthio)aniline and
                      2-hydroxy-3-methoxybenzaldehyde (HL·SMe = C15H15NO2S), was
                      synthesized and fully characterized. The magnetic properties
                      of the charge-neutral {CuLn} complexes are dominated by
                      ferromagnetic CuII–LnIII exchange interactions. Large-area
                      electron transport studies reveal that the average
                      conductivity of robust, self-assembled {CuLn} monolayers on
                      a gold substrate is significantly lower than that of common
                      alkanethiolates. Theoretical calculations of transmission
                      spectra of individual complexes 1 and 4 embedded between two
                      metallic electrodes show that the molecular
                      current–voltage (I–V) characteristics are strongly
                      influenced by electron transport through the Cu centers and
                      thus fully independent of the lanthanide ion, in excellent
                      agreement with the experimental I–V data for 1–4. The
                      β-polarized transmission indicated by calculations of 1 and
                      4 points out their potential as spin filters. In addition,
                      the reactivity of the title compound 1 with CuII in a
                      square-pyramidal coordination environment toward methanolate
                      and azide was examined, resulting in the formation of a
                      linear trinuclear complex, [Cu2Na(L·SMe)4]NO3·3MeOH (5),
                      characterized by antiferromagnetic exchange interactions
                      between the two copper ions.},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {522 - Controlling Spin-Based Phenomena (POF3-522)},
      pid          = {G:(DE-HGF)POF3-522},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:30040402},
      UT           = {WOS:000441477100069},
      doi          = {10.1021/acs.inorgchem.8b01279},
      url          = {https://juser.fz-juelich.de/record/858631},
}