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| 005 | 20240619083549.0 | ||
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| 037 | _ | _ | |a FZJ-2018-07739 |
| 041 | _ | _ | |a English |
| 100 | 1 | _ | |a Stiakakis, Emmanuel |0 P:(DE-Juel1)130987 |b 0 |e Corresponding author |
| 111 | 2 | _ | |a Juelich Soft Matter Days |c Jülich |d 2018-11-20 - 2018-11-23 |w Germany |
| 245 | _ | _ | |a Molecular engineering of model soft-matter systems using DNA |
| 260 | _ | _ | |c 2018 |
| 336 | 7 | _ | |a Conference Paper |0 33 |2 EndNote |
| 336 | 7 | _ | |a Other |2 DataCite |
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| 520 | _ | _ | |a DNA is widely recognized as a promising engineering material in the field of nanotechnology and material science. Here, I will show that using DNA as building block for constructing molecules with complex architecture in the field of soft matter can offer a great opportunity to obtain well-defined monodisperse systems with a wide variety of particle shape, stiffness, charge, etc. A small library of well-defined DNA-based macromolecular assemblies will be presented, focused on an all-DNA chain-stick construct which consists of a gapped DNA duplex - with contour length near DNA’s persistence length - where two stiff double-stranded DNA segments of equal length are connected by a single-stranded flexible spacer. Trough a combined experimental and numerical study, we provide unambiguous evidence for the stabilization of an unconventional smectic-A liquid crystal phase, where most of the constituent molecules attain a folded configuration. Our results demonstrate that DNA as a building block offers an exquisitely tunable means to engineer a potentially rich assortment of lyotropic liquid crystals that can be precisely designed on subnanometer level. |
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| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/858903/files/Abstract_E.Stiakakis_JSMD_2018.pdf |
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| 914 | 1 | _ | |y 2018 |
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