000859107 001__ 859107 000859107 005__ 20240712113104.0 000859107 0247_ $$2doi$$a10.1021/acs.chemrev.8b00422 000859107 0247_ $$2ISSN$$a0009-2665 000859107 0247_ $$2ISSN$$a1520-6890 000859107 0247_ $$2altmetric$$aaltmetric:52021278 000859107 0247_ $$2pmid$$apmid:30500179 000859107 0247_ $$2WOS$$aWOS:000453488700005 000859107 037__ $$aFZJ-2019-00051 000859107 082__ $$a540 000859107 1001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b0$$eCorresponding author 000859107 245__ $$aBefore Li Ion Batteries 000859107 260__ $$aWashington, DC$$bACS Publ.$$c2018 000859107 3367_ $$2DRIVER$$aarticle 000859107 3367_ $$2DataCite$$aOutput Types/Journal article 000859107 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1575008319_25888 000859107 3367_ $$2BibTeX$$aARTICLE 000859107 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000859107 3367_ $$00$$2EndNote$$aJournal Article 000859107 520__ $$aThis Review covers a sequence of key discoveries and technical achievements that eventually led to the birth of the lithium-ion battery. In doing so, it not only sheds light on the history with the advantage of contemporary hindsight but also provides insight and inspiration to aid in the ongoing quest for better batteries of the future. A detailed retrospective on ingenious designs, accidental discoveries, intentional breakthroughs, and deceiving misconceptions is given: from the discovery of the element lithium to its electrochemical synthesis; from intercalation host material development to the concept of dual-intercalation electrodes; and from the misunderstanding of intercalation behavior into graphite to the comprehension of interphases. The onerous demands of bringing all critical components (anode, cathode, electrolyte, solid-electrolyte interphases), each of which possess unique chemistries, into a sophisticated electrochemical device reveal that the challenge of interfacing these originally incongruent components often outweighs the individual merits and limits in their own properties. These important lessons are likely to remain true for the more aggressive battery chemistries of future generations, ranging from a revisited Li-metal anode, to conversion-reaction type chemistries such as Li/sulfur, Li/oxygen, and metal fluorides, and to bivalent cation intercalations. 000859107 536__ $$0G:(DE-HGF)POF3-131$$a131 - Electrochemical Storage (POF3-131)$$cPOF3-131$$fPOF III$$x0 000859107 588__ $$aDataset connected to CrossRef 000859107 7001_ $$00000-0001-7493-1092$$aBarnett, Brian$$b1 000859107 7001_ $$00000-0002-6946-8635$$aXu, Kang$$b2$$eCorresponding author 000859107 773__ $$0PERI:(DE-600)2003609-7$$a10.1021/acs.chemrev.8b00422$$gVol. 118, no. 23, p. 11433 - 11456$$n23$$p11433 - 11456$$tChemical reviews$$v118$$x1520-6890$$y2018 000859107 8564_ $$uhttps://juser.fz-juelich.de/record/859107/files/acs.chemrev.8b00422.pdf$$yRestricted 000859107 8564_ $$uhttps://juser.fz-juelich.de/record/859107/files/acs.chemrev.8b00422.pdf?subformat=pdfa$$xpdfa$$yRestricted 000859107 909CO $$ooai:juser.fz-juelich.de:859107$$pVDB 000859107 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166130$$aForschungszentrum Jülich$$b0$$kFZJ 000859107 9131_ $$0G:(DE-HGF)POF3-131$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lSpeicher und vernetzte Infrastrukturen$$vElectrochemical Storage$$x0 000859107 9141_ $$y2019 000859107 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz 000859107 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bCHEM REV : 2017 000859107 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS 000859107 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline 000859107 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database 000859107 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search 000859107 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC 000859107 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List 000859107 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index 000859107 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection 000859107 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded 000859107 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences 000859107 915__ $$0StatID:(DE-HGF)9950$$2StatID$$aIF >= 50$$bCHEM REV : 2017 000859107 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x0 000859107 980__ $$ajournal 000859107 980__ $$aVDB 000859107 980__ $$aI:(DE-Juel1)IEK-12-20141217 000859107 980__ $$aUNRESTRICTED 000859107 981__ $$aI:(DE-Juel1)IMD-4-20141217