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@INPROCEEDINGS{Izumoto:859327,
author = {Izumoto, Satoshi and Huisman, Johan Alexander and
Zimmermann, Egon and Esser, Odilia and Haegel, Franz-Hubert
and Vereecken, Harry},
title = {{S}pectral induced polarization response of calcite
precipitation},
reportid = {FZJ-2019-00196},
year = {2018},
abstract = {Induced calcite precipitation is used in a range of
geotechnical applications to improve the mechanical
properties of porous media. It has been shown that spectral
induced polarization (SIP) allows to monitor calcite
precipitation, although results were partly inconsistent.
Therefore, this study aims to investigate how the SIP
response of calcite depends on solute composition, since
this may explain the differences in previous studies. SIP
measurements were made on a column filled with sand while
calcite precipitation was created by injecting Na2CO3 and
CaCl2 solutions through two different ports. The experiment
consisted of five phases. In phase I, calcite precipitation
was generated for a period of 12 days. This resulted in a
well-defined calcite precipitation front, which was
associated with an increase in the imaginary conductivity.
In phase II, the injected solutions were increasingly
diluted. This resulted in a clear decrease in imaginary
conductivity. In phase III, the injection of the two
solutions was stopped. Nevertheless, calcite precipitation
continued and solute concentrations in the mixing zone
decreased. As in phase II, this led to a decrease in the
imaginary conductivity. In phase IV, the injection rate of
the Na2CO3 solution was reduced to shift the mixing zone,
which also decreased the imaginary conductivity. Finally,
the column was flushed with a solution in equilibrium with
calcite in phase V, which led to a very small SIP signal.
These results imply that calcite only generates a SIP
response when it is in contact with solution which is
strongly oversaturated with respect to calcite.},
month = {Oct},
date = {2018-10-03},
organization = {5th International Workshop on Induced
Polarization, Newark (USA), 3 Oct 2018
- 5 Oct 2018},
subtyp = {After Call},
cin = {IBG-3 / ZEA-2},
cid = {I:(DE-Juel1)IBG-3-20101118 / I:(DE-Juel1)ZEA-2-20090406},
pnm = {255 - Terrestrial Systems: From Observation to Prediction
(POF3-255) / ENIGMA - European training Network for In situ
imaGing of dynaMic processes in heterogeneous subsurfAce
environments (722028)},
pid = {G:(DE-HGF)POF3-255 / G:(EU-Grant)722028},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/859327},
}