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@INPROCEEDINGS{Chatterji:859540,
author = {Chatterji, T. and Brown, P. J. and Sazonov, Andrew and
Thoma, Henrik and Deng, H. and Roth, G. and Hutanu,
Vladimir},
title = {{S}pin reorientation transition about 50 {K} in
{H}o{F}e{O}3 studied by polarised neutron diffraction on
{POLI}},
reportid = {FZJ-2019-00392},
year = {2018},
abstract = {The onset of electric polarization is observed in HoFeO3
below 210 K [1]. Previous neutron diffraction measurements
in zero field indicate that magnetic structure do not change
from RT down to about 55 K where a spin reorientation
transition from a weak ferromagnetic (WF) AFM structure with
μ(Fe) ║ [010] and μ(Ho) = 0 (Γ4 symmetry) to μ(Fe) ║
[100] and μ(Ho) ≈ 0 (Γ1 symmetry) occur [2]. Polarized
neutron studies [3] have shown that 9 T applied parallel to
[001] at 70 K aligns a moment of magnitude ≈ 1 μB which
is almost entirely due to Ho whilst leaving the arrangement
of Fe moments in the WF1 structure with Γ4 symmetry
essentially unchanged. New polarised neutron diffraction
setup using novel high-Tc superconductor compact magnet with
maximal field up to 2.2 T has been recently implemented on
POLI [4]. Using this setup the evolution of the magnetic
structure in HoFeO3 with temperature and field in the range
46-70 K and 0.15-2.2 T were studied using two wavelengths of
0.71 Å and 1.15 Å in cooling and heating cycles
respectively. The results from POLI are compatible with the
previous data. Above 53 K Γ4 WF model with magnetic moments
on Fe directed along [010] could be confirmed. Interestingly
that in this phase only one WF domain could be identified
even by the lowest field. Below 53 K for the lowest field
0.15 T almost equal population of opposing 180◦ domains
was found, and it is strongly field dependent. The
application of the field also lowers the temperature of the
transition, until in 2.2 T it does not occur above 47 K.
Significant components of the magnetic moment on Fe along
[001] could be identified at the intermediate fields of
about 1 T below 53 K, indicating that reorientation
transition breaks orthorombic symmetry. The resulting
monoclinic phase determined from polarised neutron
diffraction is a coherent combination of the Γ1 and Γ4
structures rather than just a mixture of two phases.
References:[1] S. Giri et al. (unpublished results) [2] T.
Chatterji, M. Meven, and P. J. Brown (2017) AIP Advances 7
045106.[3] T. Chatterji, A. Stunault and P. J. Brown (2017)
J. Phys.: Condens. Matter 29 385802.[4] H. Thoma, W.
Luberstetter, J. Peters and V. Hutanu (2018) J. Appl. Cryst.
51 17.},
month = {Jul},
date = {2018-07-03},
organization = {Polarised Neutrons for
Condensed-Matter Investigations 2018,
Abingdon (England), 3 Jul 2018 - 6 Jul
2018},
subtyp = {After Call},
cin = {JCNS-FRM-II / JCNS-2 / JARA-FIT},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-2-20110106 / $I:(DE-82)080009_20140620$},
pnm = {524 - Controlling Collective States (POF3-524) / 6212 -
Quantum Condensed Matter: Magnetism, Superconductivity
(POF3-621) / 6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich
Centre for Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-524 / G:(DE-HGF)POF3-6212 /
G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)POLI-HEIDI-20140101 /
EXP:(DE-MLZ)HEIDI-20140101},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/859540},
}