001     859569
005     20210130000327.0
037 _ _ |a FZJ-2019-00421
041 _ _ |a English
100 1 _ |a Lott, Dieter
|0 P:(DE-HGF)0
|b 0
|e Corresponding author
111 2 _ |a German Conference for Research with Synchrotron Radiation, Neutrons and Ion Beams at Large Facilities
|g SNI2018
|c Garching
|d 2019-09-17 - 2019-09-19
|w Germany
245 _ _ |a Diffusion of iron in the near-surface region of magnetite (001)
260 _ _ |c 2018
336 7 _ |a Conference Paper
|0 33
|2 EndNote
336 7 _ |a Other
|2 DataCite
336 7 _ |a INPROCEEDINGS
|2 BibTeX
336 7 _ |a conferenceObject
|2 DRIVER
336 7 _ |a LECTURE_SPEECH
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336 7 _ |a Conference Presentation
|b conf
|m conf
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|s 1547736584_16920
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|x After Call
520 _ _ |a The mobility of Fe in magnetite is a key ingredient towards a better understanding of its defect structure and resulting properties. For nanoparticles, which find a range of applications in medicine, spintronics, material science and catalysis, the near-surface is particularly important. Recent scanning tunnelling microscopy (STM) and low energy electron dif- fraction (LEED) studies of the ( √2× √2)R45° reconstructed (001) surface suggested a subsurface vacancy stabilisation model for this surface, later proved by surface x-ray diffraction (SXRD) [1,2]. Low energy electron microscopy (LEEM) experiments under catalytic conditions showed a regrowth process of Fe3O4-layers on (001) surfaces [3]. These results point towards an interesting interplay between cation vacancy formation and diffusion. We present the results of iron exchange at the interface between 57Fe3O4 thin-films and a Fe3O4 (001) substrate after ultra high vacuum annealing at multiple temperatures. By exploiting the scattering length variation of 57Fe and natural Fe, its interdiffusion across the film-substrate interface is characterized by neutron reflectometry at MARIA at MLZ [4]. The results on growth and diffusion are complemented by x-ray reflectometry data.[1] Bliem, R. et al. Science. 346, 1215 (2014)[2] Arndt, B. et al. Surf. Sci. 653, 76 (2016)[3] Nie, S. et al., J. Am. Chem. Soc. 135, 10091 (2013) [4] Schmidt, H. et al. Adv. Eng. Mat. 11, 446 (2009)
536 _ _ |0 G:(DE-HGF)POF3-6G15
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|c POF3-6G15
|a 6G15 - FRM II / MLZ (POF3-6G15)
536 _ _ |a 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
|0 G:(DE-HGF)POF3-6G4
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650 2 7 |a Magnetism
|0 V:(DE-MLZ)SciArea-170
|2 V:(DE-HGF)
|x 0
650 1 7 |a Magnetic Materials
|0 V:(DE-MLZ)GC-1604-2016
|2 V:(DE-HGF)
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693 _ _ |0 EXP:(DE-MLZ)MBE-MLZ-20151210
|5 EXP:(DE-MLZ)MBE-MLZ-20151210
|e MBE-MLZ: Molecular Beam Epitaxy at MLZ
|x 0
693 _ _ |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
|e MARIA: Magnetic reflectometer with high incident angle
|f NL5N
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|5 EXP:(DE-MLZ)MARIA-20140101
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|x 1
700 1 _ |a Vonk, Vedran
|0 P:(DE-HGF)0
|b 1
700 1 _ |a Creutzburg, Marcus
|0 P:(DE-HGF)0
|b 2
700 1 _ |a Syed Mohd, Amir
|0 P:(DE-Juel1)159309
|b 3
|u fzj
700 1 _ |a Pütter, Sabine
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|b 4
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700 1 _ |a Koutsioumpas, Alexandros
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700 1 _ |a Mattauch, Stefan
|0 P:(DE-Juel1)130821
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|u fzj
700 1 _ |a Stierle, Andreas
|0 P:(DE-HGF)0
|b 7
909 C O |o oai:juser.fz-juelich.de:859569
|p VDB:MLZ
|p VDB
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 3
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910 1 _ |a Forschungszentrum Jülich
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910 1 _ |a Forschungszentrum Jülich
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910 1 _ |a Forschungszentrum Jülich
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|b Forschungsbereich Materie
|l Großgeräte: Materie
913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|1 G:(DE-HGF)POF3-620
|0 G:(DE-HGF)POF3-623
|2 G:(DE-HGF)POF3-600
|v Facility topic: Neutrons for Research on Condensed Matter
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914 1 _ |y 2018
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)JCNS-FRM-II-20110218
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920 1 _ |0 I:(DE-Juel1)JCNS-2-20110106
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980 _ _ |a conf
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)JCNS-FRM-II-20110218
980 _ _ |a I:(DE-Juel1)JCNS-2-20110106
980 _ _ |a UNRESTRICTED


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