000859588 001__ 859588
000859588 005__ 20240711085647.0
000859588 0247_ $$2doi$$a10.1021/acs.inorgchem.7b02980
000859588 0247_ $$2ISSN$$a0020-1669
000859588 0247_ $$2ISSN$$a1520-510X
000859588 0247_ $$2pmid$$apmid:29537828
000859588 0247_ $$2WOS$$aWOS:000429283200028
000859588 0247_ $$2altmetric$$aaltmetric:34347663
000859588 037__ $$aFZJ-2019-00437
000859588 082__ $$a540
000859588 1001_ $$00000-0002-6527-3961$$aAlahmari, Fatimah$$b0$$eCorresponding author
000859588 245__ $$aThioaluminogermanate M(AlS2)(GeS2)4 (M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27Al and 23Na NMR Spectroscopy
000859588 260__ $$aWashington, DC$$bAmerican Chemical Society$$c2018
000859588 3367_ $$2DRIVER$$aarticle
000859588 3367_ $$2DataCite$$aOutput Types/Journal article
000859588 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1547818357_9364
000859588 3367_ $$2BibTeX$$aARTICLE
000859588 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000859588 3367_ $$00$$2EndNote$$aJournal Article
000859588 520__ $$aThe new thioaluminogermanate Na(AlS2)(GeS2)4 (1) was successfully synthesized by a direct combination reaction. The compound crystallizes in the monoclinic space group P21/n (no. 14) with unit cell parameters a = 6.803(3) Å, b = 38.207(2) Å, c = 6.947(4) Å, and β = 119.17(3)°. The crystal structure is composed of a [(AlS2)(GeS2)4]− 3D polyanionic network, in which Al and Ge atoms share the atomic positions and Na cations occupy the channels and voids formed by the connection of (Ge/Al)S4 tetrahedra. The title compound shows a cation-exchange property with monovalent Ag+ and Cu+ ions at room temperature in solvent media, resulting in the formation of the isostructural compounds Ag(AlS2)(GeS2)4 (2) and Cu(AlS2)(GeS2)4 (3), respectively. The ion-exchange products Ag(AlS2)(GeS2)4 (2) and Cu(AlS2)(GeS2)4 (3) show higher air stability and narrower bandgap energies compared to those of the parent compound Na(AlS2)(GeS2)4 (1).
000859588 536__ $$0G:(DE-HGF)POF3-131$$a131 - Electrochemical Storage (POF3-131)$$cPOF3-131$$fPOF III$$x0
000859588 588__ $$aDataset connected to CrossRef
000859588 7001_ $$0P:(DE-Juel1)174080$$aDavaasuren, Bambar$$b1$$ufzj
000859588 7001_ $$0P:(DE-HGF)0$$aEmwas, Abdul-Hamid$$b2
000859588 7001_ $$0P:(DE-HGF)0$$aRothenberger, Alexander$$b3
000859588 773__ $$0PERI:(DE-600)1484438-2$$a10.1021/acs.inorgchem.7b02980$$gVol. 57, no. 7, p. 3713 - 3719$$n7$$p3713 - 3719$$tInorganic chemistry$$v57$$x1520-510X$$y2018
000859588 8564_ $$uhttps://juser.fz-juelich.de/record/859588/files/acs.inorgchem.7b02980.pdf$$yRestricted
000859588 8564_ $$uhttps://juser.fz-juelich.de/record/859588/files/acs.inorgchem.7b02980.pdf?subformat=pdfa$$xpdfa$$yRestricted
000859588 909CO $$ooai:juser.fz-juelich.de:859588$$pVDB
000859588 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)174080$$aForschungszentrum Jülich$$b1$$kFZJ
000859588 9131_ $$0G:(DE-HGF)POF3-131$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lSpeicher und vernetzte Infrastrukturen$$vElectrochemical Storage$$x0
000859588 9141_ $$y2018
000859588 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000859588 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bINORG CHEM : 2017
000859588 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000859588 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000859588 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000859588 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search
000859588 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC
000859588 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List
000859588 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000859588 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000859588 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000859588 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000859588 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5
000859588 920__ $$lyes
000859588 9201_ $$0I:(DE-Juel1)IEK-1-20101013$$kIEK-1$$lWerkstoffsynthese und Herstellungsverfahren$$x0
000859588 980__ $$ajournal
000859588 980__ $$aVDB
000859588 980__ $$aI:(DE-Juel1)IEK-1-20101013
000859588 980__ $$aUNRESTRICTED
000859588 981__ $$aI:(DE-Juel1)IMD-2-20101013