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100 | 1 | _ | |a Alahmari, Fatimah |0 0000-0002-6527-3961 |b 0 |e Corresponding author |
245 | _ | _ | |a Thioaluminogermanate M(AlS2)(GeS2)4 (M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27Al and 23Na NMR Spectroscopy |
260 | _ | _ | |a Washington, DC |c 2018 |b American Chemical Society |
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520 | _ | _ | |a The new thioaluminogermanate Na(AlS2)(GeS2)4 (1) was successfully synthesized by a direct combination reaction. The compound crystallizes in the monoclinic space group P21/n (no. 14) with unit cell parameters a = 6.803(3) Å, b = 38.207(2) Å, c = 6.947(4) Å, and β = 119.17(3)°. The crystal structure is composed of a [(AlS2)(GeS2)4]− 3D polyanionic network, in which Al and Ge atoms share the atomic positions and Na cations occupy the channels and voids formed by the connection of (Ge/Al)S4 tetrahedra. The title compound shows a cation-exchange property with monovalent Ag+ and Cu+ ions at room temperature in solvent media, resulting in the formation of the isostructural compounds Ag(AlS2)(GeS2)4 (2) and Cu(AlS2)(GeS2)4 (3), respectively. The ion-exchange products Ag(AlS2)(GeS2)4 (2) and Cu(AlS2)(GeS2)4 (3) show higher air stability and narrower bandgap energies compared to those of the parent compound Na(AlS2)(GeS2)4 (1). |
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773 | _ | _ | |a 10.1021/acs.inorgchem.7b02980 |g Vol. 57, no. 7, p. 3713 - 3719 |0 PERI:(DE-600)1484438-2 |n 7 |p 3713 - 3719 |t Inorganic chemistry |v 57 |y 2018 |x 1520-510X |
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