Home > Publications database > Layered copper thioaluminate K2Cu3AlS4: Synthesis, crystal structure, characterization and solid-state 27Al and 39K NMR studies > print

001     859589
005     20240708132854.0
024 7 _ |a 10.1016/j.jallcom.2018.10.239
|2 doi
024 7 _ |a 0925-8388
|2 ISSN
024 7 _ |a 1873-4669
|2 ISSN
024 7 _ |a WOS:000453826200119
|2 WOS
037 _ _ |a FZJ-2019-00438
082 _ _ |a 540
100 1 _ |a Alahmari, Fatimah
|0 0000-0002-6527-3961
|b 0
|e Corresponding author
245 _ _ |a Layered copper thioaluminate K2Cu3AlS4: Synthesis, crystal structure, characterization and solid-state 27Al and 39K NMR studies
260 _ _ |a Amsterdam [u.a.]
|c 2019
|b ScienceDirect
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1547818134_26260
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a The first example of alkali/transition metal thioaluminates K2Cu3AlS4 was synthesized and characterized. The compound crystallizes in the orthorhombic space group Pnna (no. 52), with unit cell parameters a = 5.471 (6) Å, b = 5.468 (6) Å and c = 13.111 (1) Å, within a pseudo-tetragonal lattice. Its crystal structure consists of 2D [Cu3AlS4]2- polyanionic anti-PbO type layers, in which Al and Cu atoms share the atomic positions, separated by K+ cations. The (Cu/Al) atomic positions are tetrahedrally coordinated by S atoms, whereas K atoms are surrounded by eight S atoms in a cubic fashion. The coordination environments of the Al and K cations were confirmed by solid-state 27Al and 39K NMR, respectively. The title compound is a semiconductor with a direct bandgap of 2.96 eV, and thermally stable up to 550 °C
536 _ _ |a 131 - Electrochemical Storage (POF3-131)
|0 G:(DE-HGF)POF3-131
|c POF3-131
|f POF III
|x 0
588 _ _ |a Dataset connected to CrossRef
700 1 _ |a Dey, Somnath
|0 P:(DE-HGF)0
|b 1
700 1 _ |a Emwas, Abdul-Hamid
|0 P:(DE-HGF)0
|b 2
700 1 _ |a Davaasuren, Bambar
|0 P:(DE-Juel1)174080
|b 3
|u fzj
700 1 _ |a Rothenberger, Alexander
|0 P:(DE-HGF)0
|b 4
773 _ _ |a 10.1016/j.jallcom.2018.10.239
|g Vol. 776, p. 1041 - 1047
|0 PERI:(DE-600)2012675-X
|p 1041 - 1047
|t Journal of alloys and compounds
|v 776
|y 2019
|x 0925-8388
909 C O |o oai:juser.fz-juelich.de:859589
|p VDB
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 3
|6 P:(DE-Juel1)174080
913 1 _ |a DE-HGF
|l Speicher und vernetzte Infrastrukturen
|1 G:(DE-HGF)POF3-130
|0 G:(DE-HGF)POF3-131
|2 G:(DE-HGF)POF3-100
|v Electrochemical Storage
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
|b Energie
914 1 _ |y 2019
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b J ALLOY COMPD : 2017
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0600
|2 StatID
|b Ebsco Academic Search
915 _ _ |a Peer Review
|0 StatID:(DE-HGF)0030
|2 StatID
|b ASC
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
915 _ _ |a WoS
|0 StatID:(DE-HGF)0110
|2 StatID
|b Science Citation Index
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
915 _ _ |a WoS
|0 StatID:(DE-HGF)0111
|2 StatID
|b Science Citation Index Expanded
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |a IF < 5
|0 StatID:(DE-HGF)9900
|2 StatID
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)IEK-1-20101013
|k IEK-1
|l Werkstoffsynthese und Herstellungsverfahren
|x 0
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)IEK-1-20101013
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IMD-2-20101013

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21