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@ARTICLE{Fitzgerald:859641,
author = {Fitzgerald, Barry W. and den Otter, Wouter K. and Luding,
Stefan and Briels, Willem},
title = {{M}esoscale {S}imulations of the {R}heology of {F}illed
{S}tyrene-{B}utadiene {C}ompounds},
journal = {Macromolecular theory and simulations},
volume = {27},
number = {5},
issn = {1022-1344},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2019-00489},
pages = {1800014 -},
year = {2018},
abstract = {The ability of a highly coarse‐grained polymer model is
explored to simulate the impact of carbon black (CB) filler
concentration on the rheological properties of unvulcanized
styrene–butadiene melts—an intermediate stage in the
production of styrene–butadiene rubber (SBR) commonly used
in tyres. Responsive particle dynamics (RaPiD), previously
used to study dilute polymeric systems, models entire
polymers as single particles interacting through a
combination of conservative interactions and transient
entanglement‐mimicking forces. The simulation parameters
are tuned to the linear rheology of the unfilled melt, as
measured using a rubber process analyzer (RPA). For the
filled compounds, only the interaction between the polymers
and fillers is varied. On top of excluded volume
interactions, a slight attraction (≈0.1 kBT) between
polymers and fillers is required to attain agreement with
RPA measurements. The physical origins of the small strength
of this interaction are discussed. This method offers
potential for future numerical investigations of filled
melts.},
cin = {ICS-3},
ddc = {540},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551)},
pid = {G:(DE-HGF)POF3-551},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000444679600001},
doi = {10.1002/mats.201800014},
url = {https://juser.fz-juelich.de/record/859641},
}