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024 7 _ |a 10.1103/PhysRevB.98.155133
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024 7 _ |a 1098-0121
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024 7 _ |a 1538-4489
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024 7 _ |a 1550-235X
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024 7 _ |a 2469-9950
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024 7 _ |a 2469-9969
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100 1 _ |a Kuo, Cheng-Tai
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245 _ _ |a Atomic-layer-resolved composition and electronic structure of the cuprate B i 2 S r 2 CaC u 2 O 8 + δ from soft x-ray standing-wave photoemission
260 _ _ |a Woodbury, NY
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520 _ _ |a A major remaining challenge in the superconducting cuprates is the unambiguous differentiation of the composition and electronic structure of the CuO2 layers and those of the intermediate layers. The large c axis for these materials permits employing soft x-ray (930.3 eV) standing wave (SW) excitation in photoemission that yields atomic layer-by-layer depth resolution of these properties. Applying SW photoemission to Bi2Sr2CaCu2O8+δ yields the depth distribution of atomic composition and the layer-resolved densities of states. We detect significant Ca presence in the SrO layers and oxygen bonding to three different cations. The layer-resolved valence electronic structure is found to be strongly influenced by the atomic supermodulation structure, as determined by comparison to density functional theory calculations, by Ca-Sr intermixing, and by correlation effects associated with the Cu 3d−3d Coulomb interaction, further clarifying the complex interactions in this prototypical cuprate. Measurements of this type for other quasi-two-dimensional materials with large c represent a promising future direction.
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773 _ _ |a 10.1103/PhysRevB.98.155133
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