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@ARTICLE{Lezov:859745,
author = {Lezov, A. A. and Gubarev, A. S. and Podsevalnikova, A. N.
and Senchukova, A. S. and Lebedeva, E. V. and Dudkina, M. M.
and Tenkovtsev, A. V. and Nekrasova, T. N. and Andreeva, L.
N. and Smyslov, R. Yu. and Gorshkova, Yu. E. and Kopitsa, G.
P. and Radulescu, Aurel and Pipich, Vitaliy and Tsvetkov, N.
V.},
title = {{T}emperature-responsive star-shaped
poly(2-ethyl-2-oxazoline) and poly(2-isopropyl-2-oxazoline)
with central thiacalix[4]arene fragments: structure and
properties in solutions},
journal = {Colloid $\&$ polymer science},
volume = {297},
number = {2},
issn = {1435-1536},
address = {Heidelberg},
publisher = {Springer},
reportid = {FZJ-2019-00582},
pages = {285 - 296},
year = {2019},
abstract = {Temperature-responsive star-shaped
poly(2-ethyl-2-oxazoline) (star-PETOX) and
poly(2-isopropyl-2-oxazoline) (star-PIPOX) with arms grafted
to the lower rim of thiacalix[4]arene were studied in
solutions by viscometry, sedimentation velocity, light
scattering, and small-angle neutron scattering. The
experiments were carried out in water and tetrahydrofuran
solutions. It was revealed that in tetrahydrofuran, the
studied polymers were present only as individual molecules,
while in aqueous solutions, in addition to individual
molecules, large polymer aggregates were found. Molecular
characteristics of the star-PETOX and star-PIPOX samples
were estimated; their behavior in tetrahydrofuran and water
was studied over a wide temperature range. It was
established that a cloud point of the aqueous solution of
star-PETOX (67 °C) is higher than that of a solution of
star-PIPOX (35 °C). Comparison of the data obtained by
dynamic light scattering and small-angle neutron scattering
turned out to be fruitful in revealing all the structural
levels of the organization of star-PETOX and star-PIPOX in
aqueous solutions. They include the level of the individual
macromolecules and the level of supramolecular organization
with a star-like architecture.},
cin = {JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6G15 - FRM II / MLZ (POF3-6G15)},
pid = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
experiment = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-MLZ)KWS3-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000456185100010},
doi = {10.1007/s00396-018-4458-9},
url = {https://juser.fz-juelich.de/record/859745},
}