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@ARTICLE{Bugrov:859758,
      author       = {Bugrov, Alexander N. and Zavialova, Anastasia Yu. and
                      Smyslov, Ruslan Yu. and Anan'eva, Tatyana D. and Vlasova,
                      Elena N. and Mokeev, Maxim V. and Kryukov, Artem E. and
                      Kopitsa, Gennady P. and Pipich, Vitaliy},
      title        = {{L}uminescence of {E}u 3+ ions in hybrid polymer-inorganic
                      composites based on poly(methyl methacrylate) and zirconia
                      nanoparticles},
      journal      = {Luminescence},
      volume       = {33},
      number       = {5},
      issn         = {1522-7235},
      address      = {New York, NY},
      publisher    = {Wiley Interscience},
      reportid     = {FZJ-2019-00595},
      pages        = {837 - 849},
      year         = {2018},
      abstract     = {Spherical nanoparticles of ZrO2 with 2 and 10 $mol\%$
                      EuO1.5 up to 20 nm size were prepared by the method of
                      hydrothermal synthesis for luminescent functionalization of
                      the polymer–inorganic nanocomposites based on poly(methyl
                      methacrylate). Surface modification of oxide nanoparticles
                      was carried out by 3‐(trimethoxysilyl)propyl methacrylate,
                      dimethoxymethylvinyl silane and 2‐hydroxyethyl
                      methacrylate to provide uniform distribution and to prevent
                      agglomeration of nanosized filler in the polymer matrix.
                      Polymer–inorganic composites were synthesized by in situ
                      free radical polymerization in bulk. Structuring of
                      ZrO2‐EuO1.5 nanoparticles in the poly(methyl methacrylate)
                      was studied by very‐small‐angle neutron scattering.
                      According to the results, the dependence of photoluminescent
                      properties of ZrO2‐EuO1.5 nanoparticles on the content of
                      lanthanide, the symmetry of the crystal field, surface
                      treatment and the polymer matrix were established. A
                      correlation was shown between Stark splitting in
                      luminescence spectra of ZrO2‐EuO1.5 nanoparticles and
                      their phase composition. Using MMT‐assay it was shown that
                      composites based on poly(methyl methacrylate) and
                      ZrO2‐EuO1.5 nanoparticles do not have cytotoxic
                      properties, which makes it possible to use them as
                      prosthesis materials with contrasted and luminescent imaging
                      properties.},
      cin          = {JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6G15 - FRM II / MLZ (POF3-6G15)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
      experiment   = {EXP:(DE-MLZ)KWS3-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29683250},
      UT           = {WOS:000437743000002},
      doi          = {10.1002/bio.3476},
      url          = {https://juser.fz-juelich.de/record/859758},
}