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@ARTICLE{Yu:859869,
author = {Yu, Shicheng and Schmohl, Sebastian and Liu, Zigeng and
Hoffmeyer, Marija and Schön, Nino and Hausen, Florian and
Tempel, Hermann and Kungl, Hans and Wiemhofer, Hans-Dieter
and Eichel, Rüdiger},
title = {{I}nsights on {L}ayered {H}ybrid {S}olid {E}lectrolyte and
{I}ts {A}pplication in {L}ong {L}ifespan {H}igh-{V}oltage
{A}ll–{S}olid–{S}tate {L}ithium {B}attery},
journal = {Journal of materials chemistry / A Materials for energy and
sustainability A},
volume = {7},
number = {8},
issn = {2050-7496},
address = {London},
publisher = {RSC},
reportid = {FZJ-2019-00691},
pages = {3882-3894},
year = {2019},
abstract = {Direct integration of a metallic lithium anode with the
ceramic Li1.3Al0.3Ti1.7(PO4)3 (LATP) electrolyte into an
all-solid-state battery is highly challenging due to their
chemical and electrochemical incompatibility. Herein, a
layered hybrid solid electrolyte is designed by coating the
ceramic LATP electrolyte with a protective polymer
electrolyte, polyphosphazene/PVDF-HFP/LiBOB. This polymer
electrolyte comprises highly Li+ conductive polyphosphazene
and mechanically stable PVDF-HFP as the polymer matrix, and
the mobile lithium ions in the polymer layer are supplied by
LiBOB. Equipped with both polymer and ceramic components,
the hybrid electrolyte possesses favorable features, such as
a flexible surface, high ionic conductivity, high chemical
stability against lithium and wide electrochemical stability
window (4.7 V), which all to help realize its application in
all-solid-state lithium batteries. The prepared
all-solid-state battery with a metallic lithium anode and
high-voltage Li3V2(PO4)3/CNT cathode shows high capacity and
excellent cycling performance with negligible capacity loss
over 500 cycles at 50 °C. Furthermore, the analysis of the
hybrid solid electrolyte after long-term cycling
demonstrates outstanding electrode/electrolyte interfacial
stability. This study suggests that use of solid
organic–inorganic hybrid electrolyte is a promising
approach to circumvent the mechanical, chemical and
electrochemical limitations at the interface of electrodes
and ceramic electrolyte for all-solid-state batteries.},
cin = {IEK-9},
ddc = {530},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000459331600041},
doi = {10.1039/C8TA11259B},
url = {https://juser.fz-juelich.de/record/859869},
}