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@ARTICLE{Shanbogh:859920,
      author       = {Shanbogh, Pradeep P. and Raghunathan, Rajamani and Swain,
                      Diptikanta and Feygenson, Mikhail and Neuefeind, Joerg and
                      Plaisier, Jasper and Narayana, Chandrabhas and Rao, Ashok
                      and Sundaram, Nalini G.},
      title        = {{I}mpact of {A}verage, {L}ocal, and {E}lectronic
                      {S}tructure on {V}isible {L}ight {P}hotocatalysis in {N}ovel
                      {B}i{REWO} 6 ({RE} = {E}u and {T}b) {N}anomaterials},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {10},
      number       = {42},
      issn         = {1944-8252},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2019-00736},
      pages        = {35876 - 35887},
      year         = {2018},
      abstract     = {Crystal structures of hydrothermally synthesized BiEuWO6
                      and BiTbWO6 nanomaterials are deduced for the first time by
                      combined Rietveld refinement of neutron and synchrotron data
                      using the ordered and disordered models available in
                      literature. The ordered model is validated for the average
                      structure of these nanomaterials, and it is further
                      supported by the local structure analysis using neutron pair
                      distribution function. Nanomaterials are characterized by
                      field-emission scanning electron microscopy, transmission
                      electron microscopy, Brunauer–Emmett–Teller surface
                      area, diffused reflectance spectroscopy, and Raman
                      Spectroscopy. Rare-earth-substituted nanomaterials are found
                      to be efficient photocatalysts over the parent Bi2WO6 under
                      visible light irradiation for Congo-red dye degradation.
                      Particularly, BiTbWO6 shows an enhanced photocatalytic (PC)
                      activity compared to BiEuWO6, as evidenced from the
                      photoelectrochemical and time-resolved fluorescence studies.
                      The difference in the observed PC activity of these
                      nanomaterials is also explored through a detailed comparison
                      of crystal structure and electronic structure calculated
                      through the density functional theory method.},
      cin          = {Neutronenstreuung ; JCNS-1 / ICS-1},
      ddc          = {600},
      cid          = {I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551) /
                      6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6215 /
                      G:(DE-HGF)POF3-6G4},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:30264556},
      UT           = {WOS:000448754500021},
      doi          = {10.1021/acsami.8b08452},
      url          = {https://juser.fz-juelich.de/record/859920},
}