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000859959 1001_ $$00000-0001-7813-1180$$aNovak, E.$$b0
000859959 245__ $$aDynamics in the Plastic Crystalline Phases of Cyclohexanol and Cyclooctanol Studied by Quasielastic Neutron Scattering
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000859959 520__ $$aPlastic crystals are a promising candidate for solid state ionic conductors. In this work, quasielastic neutron scattering is employed to investigate the center of mass diffusive motions in two types of plastic crystalline cyclic alcohols: cyclohexanol and cyclooctanol. Two separate motions are observed which are attributed to long-range translational diffusion (α-process) and cage rattling (fast β-process). Residence times and diffusion coefficients are calculated for both processes, along with the confinement distances for the cage rattling. In addition, a binary mixture of these two materials is measured to understand how the dynamics change when a second type of molecule is added to the matrix. It is observed that, upon the addition of the larger cyclooctanol molecules into the cyclohexanol solution, the cage size decreases, which causes a decrease in the observed diffusion rates for both the α- and fast β-processes.
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000859959 7001_ $$0P:(DE-Juel1)143752$$aJalarvo, N.$$b1$$eCorresponding author
000859959 7001_ $$00000-0001-6642-3776$$aGupta, S.$$b2
000859959 7001_ $$00000-0002-2852-5111$$aHong, K.$$b3
000859959 7001_ $$0P:(DE-Juel1)172658$$aFörster, S.$$b4
000859959 7001_ $$0P:(DE-HGF)0$$aEgami, T.$$b5
000859959 7001_ $$0P:(DE-Juel1)130872$$aOhl, M.$$b6
000859959 773__ $$0PERI:(DE-600)2006039-7$$a10.1021/acs.jpcb.8b03448$$gVol. 122, no. 23, p. 6296 - 6304$$n23$$p6296 - 6304$$tThe journal of physical chemistry <Washington, DC> / B B, Condensed matter, materials, surfaces, interfaces & biophysical$$v122$$x1520-5207$$y2018
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