Home > Publications database > Dynamics in the Plastic Crystalline Phases of Cyclohexanol and Cyclooctanol Studied by Quasielastic Neutron Scattering > print

001     859959
005     20240619092117.0
024 7 _ |a 10.1021/acs.jpcb.8b03448
|2 doi
024 7 _ |a 1089-5647
|2 ISSN
024 7 _ |a 1520-5207
|2 ISSN
024 7 _ |a 1520-6106
|2 ISSN
024 7 _ |a pmid:29775540
|2 pmid
024 7 _ |a WOS:000435614000017
|2 WOS
024 7 _ |a altmetric:47740761
|2 altmetric
037 _ _ |a FZJ-2019-00765
082 _ _ |a 530
100 1 _ |a Novak, E.
|0 0000-0001-7813-1180
|b 0
245 _ _ |a Dynamics in the Plastic Crystalline Phases of Cyclohexanol and Cyclooctanol Studied by Quasielastic Neutron Scattering
260 _ _ |a Washington, DC
|c 2018
|b Soc.66306
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1548426499_28091
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a Plastic crystals are a promising candidate for solid state ionic conductors. In this work, quasielastic neutron scattering is employed to investigate the center of mass diffusive motions in two types of plastic crystalline cyclic alcohols: cyclohexanol and cyclooctanol. Two separate motions are observed which are attributed to long-range translational diffusion (α-process) and cage rattling (fast β-process). Residence times and diffusion coefficients are calculated for both processes, along with the confinement distances for the cage rattling. In addition, a binary mixture of these two materials is measured to understand how the dynamics change when a second type of molecule is added to the matrix. It is observed that, upon the addition of the larger cyclooctanol molecules into the cyclohexanol solution, the cage size decreases, which causes a decrease in the observed diffusion rates for both the α- and fast β-processes.
536 _ _ |a 551 - Functional Macromolecules and Complexes (POF3-551)
|0 G:(DE-HGF)POF3-551
|c POF3-551
|f POF III
|x 0
536 _ _ |a 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
|0 G:(DE-HGF)POF3-6G4
|c POF3-623
|f POF III
|x 1
536 _ _ |a 6215 - Soft Matter, Health and Life Sciences (POF3-621)
|0 G:(DE-HGF)POF3-6215
|c POF3-621
|f POF III
|x 2
588 _ _ |a Dataset connected to CrossRef
700 1 _ |a Jalarvo, N.
|0 P:(DE-Juel1)143752
|b 1
|e Corresponding author
700 1 _ |a Gupta, S.
|0 0000-0001-6642-3776
|b 2
700 1 _ |a Hong, K.
|0 0000-0002-2852-5111
|b 3
700 1 _ |a Förster, S.
|0 P:(DE-Juel1)172658
|b 4
700 1 _ |a Egami, T.
|0 P:(DE-HGF)0
|b 5
700 1 _ |a Ohl, M.
|0 P:(DE-Juel1)130872
|b 6
773 _ _ |a 10.1021/acs.jpcb.8b03448
|g Vol. 122, no. 23, p. 6296 - 6304
|0 PERI:(DE-600)2006039-7
|n 23
|p 6296 - 6304
|t The journal of physical chemistry / B B, Condensed matter, materials, surfaces, interfaces & biophysical
|v 122
|y 2018
|x 1520-5207
856 4 _ |u https://juser.fz-juelich.de/record/859959/files/acs.jpcb.8b03448.pdf
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/859959/files/acs.jpcb.8b03448.pdf?subformat=pdfa
|x pdfa
|y Restricted
909 C O |o oai:juser.fz-juelich.de:859959
|p VDB
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 1
|6 P:(DE-Juel1)143752
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 4
|6 P:(DE-Juel1)172658
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 6
|6 P:(DE-Juel1)130872
913 1 _ |a DE-HGF
|b Key Technologies
|l BioSoft – Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences
|1 G:(DE-HGF)POF3-550
|0 G:(DE-HGF)POF3-551
|2 G:(DE-HGF)POF3-500
|v Functional Macromolecules and Complexes
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|1 G:(DE-HGF)POF3-620
|0 G:(DE-HGF)POF3-623
|2 G:(DE-HGF)POF3-600
|v Facility topic: Neutrons for Research on Condensed Matter
|9 G:(DE-HGF)POF3-6G4
|x 1
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|1 G:(DE-HGF)POF3-620
|0 G:(DE-HGF)POF3-621
|2 G:(DE-HGF)POF3-600
|v In-house research on the structure, dynamics and function of matter
|9 G:(DE-HGF)POF3-6215
|x 2
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
914 1 _ |y 2018
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0310
|2 StatID
|b NCBI Molecular Biology Database
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0600
|2 StatID
|b Ebsco Academic Search
915 _ _ |a Peer Review
|0 StatID:(DE-HGF)0030
|2 StatID
|b ASC
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
915 _ _ |a WoS
|0 StatID:(DE-HGF)0110
|2 StatID
|b Science Citation Index
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
915 _ _ |a WoS
|0 StatID:(DE-HGF)0111
|2 StatID
|b Science Citation Index Expanded
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b J PHYS CHEM B : 2017
915 _ _ |a IF < 5
|0 StatID:(DE-HGF)9900
|2 StatID
920 1 _ |0 I:(DE-Juel1)ICS-1-20110106
|k ICS-1
|l Neutronenstreuung
|x 0
920 1 _ |0 I:(DE-Juel1)JCNS-1-20110106
|k Neutronenstreuung ; JCNS-1
|l Neutronenstreuung
|x 1
920 1 _ |0 I:(DE-Juel1)JCNS-SNS-20110128
|k JCNS-SNS
|l JCNS-SNS
|x 2
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)ICS-1-20110106
980 _ _ |a I:(DE-Juel1)JCNS-1-20110106
980 _ _ |a I:(DE-Juel1)JCNS-SNS-20110128
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IBI-8-20200312
981 _ _ |a I:(DE-Juel1)JCNS-1-20110106

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21