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@ARTICLE{Daab:859966,
      author       = {Daab, Matthias and Eichstaedt, Natalie J. and Habel,
                      Christoph and Rosenfeldt, Sabine and Kalo, Hussein and
                      Schießling, Hubert and Förster, Stephan and Breu, Josef},
      title        = {{O}nset of {O}smotic {S}welling in {H}ighly {C}harged
                      {C}lay {M}inerals},
      journal      = {Langmuir},
      volume       = {34},
      number       = {28},
      issn         = {1520-5827},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {FZJ-2019-00772},
      pages        = {8215 - 8222},
      year         = {2018},
      abstract     = {Delamination by osmotic swelling of layered materials is
                      generally thought to become increasingly difficult, if not
                      impossible, with increasing layer charge density because of
                      strong Coulomb interactions. Nevertheless, for the class of
                      2:1 layered silicates, very few examples of delaminating
                      organo-vermiculites were reported in literature. We propose
                      a mechanism for this repulsive osmotic swelling of highly
                      charged vermiculites based on repulsive counterion
                      translational entropy that dominates the interaction of
                      adjacent layers above a certain threshold separation. Based
                      on this mechanistic insight, we were able to identify
                      several organic interlayer cations appropriate to delaminate
                      highly charged, vermiculite-type clay minerals. These
                      findings suggest that the osmotic swelling of highly charged
                      organoclays is a generally applicable phenomenon rather than
                      the odd exemption.},
      cin          = {ICS-1 / Neutronenstreuung ; JCNS-1 / JCNS-FRM-II},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
                      I:(DE-Juel1)JCNS-FRM-II-20110218},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551) /
                      6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
      pid          = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
                      G:(DE-HGF)POF3-6215},
      experiment   = {EXP:(DE-MLZ)NOSPEC-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29924623},
      UT           = {WOS:000439398100009},
      doi          = {10.1021/acs.langmuir.8b00492},
      url          = {https://juser.fz-juelich.de/record/859966},
}